177573-86-3

Basic information

• Product Name: (E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane
• Synonyms: (E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane
• CAS NO: 177573-86-3
• Molecular Weight: 244.142
• Mol File: 177573-86-3.mol
• Article Data: 29

Chemical Properties

• CAS DataBase Reference: (E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane(177573-86-3)
• EPA Substance Registry System: (E)-4,4,5,5-tetramethyl-2-(3-phenylprop-1-en-1-yl)-1,3,2-dioxaborolane(177573-86-3)

Safety Data

• Hazardous Substances Data: 177573-86-3(Hazardous Substances Data)

Upstream product

• 947-91-1 Diphenylacetaldehyde 
• 78782-17-9 4,4,5,5-tetramethyl-2-[(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)methyl]-1,3,2-dioxaborolane 
• 122-78-1 phenylacetaldehyde 
• 1214264-88-6 2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,3-dihydro-1H-naphtho[1,8-de][1,3,2]diazaborinine 
• 673-32-5 1-Phenylprop-1-yne 
• 25015-63-8 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane 
• 76-09-5 2,3-dimethyl-2,3-butane diol 
• 300-57-2 allylbenzene 
• 10147-11-2 propargyl benzene 
• 73183-34-3 bis(pinacol)diborane 
• 274-07-7 benzo[1,3,2]dioxaborole 
• 55718-76-8 2-chloro-1,3,2-benzodioxaborole 
• 97-94-9 triethyl borane 
• 1313878-07-7 (E)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)allyl acetate 

Downstream Products

• 147609-46-9 2-(2E)-(3-phenyl-2-propen-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 147609-47-0 (Z)-PhCHCHCH₂BO₂(CMe₂)2 
• 84363-90-6 (1RS,2SR)-1,2-diphenyl-3-buten-1-ol 
• 177573-91-0 (E)-(3-phenylprop-1-en-1- yl)boronic acid neopentyl glycol ester 

Relevant articles and documents

Transborylation of alkenylboranes with diboranes

Exchange of boryl moieties between alkenylboranes and diboron reagents has been postulated as a stereospecific cross-metathesis pathway with concomitant formation of mixed diboron reagents. DFT calculations propose a mechanism for the stereocontrolled C(sp2)-B/B′-B′ cross-metathesis with both symmetric and non-symmetric diboron reagents. This journal is

Cs4B4O3F10: First Fluorooxoborate with [BF4] Involving Heteroanionic Units and Extremely Low Melting Point

Herein, a new congruently melting mixed-anion compound Cs4B4O3F10 has been characterized as the first fluorooxoborate with [BF4] involving heteroanionic units. Compound Cs4B4O3F10 possesses two highly fluorinated anionic clusters and therefore its formula can be expressed as Cs3(B3O3F6) ? Cs(BF4). The influence of [BF4] units on micro-symmetry and structural evolution was discussed based on the parent compound. More importantly, Cs4B4O3F10 shows the lowest melting point among all the available borates and thus sets a new record for such system. This work is of great significance to enrich and tailor the structure of borates using perfluorinated [BF4] units.

Solvent- and metal-free hydroboration of alkynes under microwave irradiation

Boronic esters are versatile building blocks extensively used in organic chemistry and essential to a variety of coupling reactions. In this work, the hydroboration reactions of alkynes were performed without metal catalysts using concomitant microwave ir