178159-74-5Relevant articles and documents
Heterogeneous asymmetric epoxidation of unfunctionalized olefins catalyzed by polymer-bound (salen)manganese complexes
Minutolo, Filippo,Pini, Dario,Petri, Antonella,Salvadori, Piero
, p. 2293 - 2302 (1996)
The synthesis of three different polymer-bound chiral Mn-salen complexes (Poly-1, -2a, -2b) is reported, along with their application as recyclable catalysts in heterogeneous asymmetric epoxidation with mCPBA/NMO of several unfunctionalized olefins. The i
Chiral manganese(III) salen catalysts immobilized on MCM-41 and delaminated zeolites ITQ-2 and ITQ-6 through new axial coordinating linkers
Dominguez, Irene,Fornes, Vicente,Sabater, Maria J.
, p. 92 - 99 (2007/10/03)
We report that the catalytic behavior and enantioselectivity of three different chiral Mn(III) salen complexes anchored to traditional supports such as MCM-41 (38-A pore diameter) and delaminated zeolitic materials ITQ-2 and ITQ-6 strongly depend on wheth