178218-29-6Relevant articles and documents
Two-carbon extension of N,N-disubstituted amides with bis(trimethylsilyl) thioketene affording N,N-disubstituted 3-oxothioamides
Tsuchiya, Tohru,Oishi, Akihiro,Shibuya, Isao,Taguchi, Yoichi,Honda, Kazumasa
, p. 1621 - 1622 (1996)
N,N-Disubstituted alkanamides cleanly react with bis(trimethylsilyl)thioketene to form N,N-disubstituted 2-trimethylsilyl-3-trimethylsilyloxyalk-2-enethioamides, which upon acid hydrolysis give N,N-disubstituted 3-oxoalkanethioamides.