178861-37-5

Basic information

• Product Name: N-(tert-butoxycarbonyl)-L-(Se)-phenylselenocysteine
• Synonyms: N-(tert-butoxycarbonyl)-L-(Se)-phenylselenocysteine
• CAS NO: 178861-37-5
• Molecular Weight: 344.269
• Mol File: 178861-37-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-(tert-butoxycarbonyl)-L-(Se)-phenylselenocysteine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(tert-butoxycarbonyl)-L-(Se)-phenylselenocysteine(178861-37-5)
• EPA Substance Registry System: N-(tert-butoxycarbonyl)-L-(Se)-phenylselenocysteine(178861-37-5)

Safety Data

• Hazardous Substances Data: 178861-37-5(Hazardous Substances Data)

Upstream product

• 1666-13-3 diphenyl diselenide 
• 98541-64-1 N-(tert-butyloxycarbonyl)-D-serine β-lactone 
• 23974-72-3 sodium phenylselenide 

Downstream Products

• 204329-92-0 (S)-2-{(S)-2-[(S)-2-((S)-2-tert-Butoxycarbonylamino-3-phenylselanyl-propionylamino)-propionyloxy]-3-methyl-butyrylamino}-5-[4-(3-trifluoromethyl-3H-diazirin-3-yl)-phenyl]-pentanoic acid tert-butyl ester 
• 178861-43-3 (3S,6S,9S,12S)-12-Isopropyl-9-[3-(4-methoxy-phenyl)-propyl]-3-methyl-6-phenylselanylmethyl-1-oxa-4,7,10-triaza-cyclododecane-2,5,8,11-tetraone 
• 198275-45-5 (S)-2-{(S)-2-[(S)-2-((S)-2-Amino-3-phenylselanyl-propionylamino)-propionyloxy]-3-methyl-butyrylamino}-5-(10-methoxy-anthracen-9-yl)-pentanoic acid 
• 198275-46-6 (3S,6S,9S,12S)-12-Isopropyl-9-[3-(10-methoxy-anthracen-9-yl)-propyl]-3-methyl-6-phenylselanylmethyl-1-oxa-4,7,10-triaza-cyclododecane-2,5,8,11-tetraone 
• 324538-04-7 (S)-2-amino-3-phenylselenylpropan-1-ol 
• 575488-58-3 Boc-D-PhSeAla-L-Ala-L-Val-L-Amp-OtBu 
• 338735-90-3 2-{2-[2-(2-tert-butoxycarbonylamino-3-phenylselanyl-propionylamino)-propionyloxy]-3-methyl-butyrylamino}-5-[2-nitro-4-(3-trifluoromethyl-3H-diazirin-3-yl)-phenyl]-pentanoic acid tert-butyl ester 
• 338735-99-2 2-{2-[2-(2-tert-butoxycarbonylamino-3-phenylselanyl-propionylamino)-propionyloxy]-3-methyl-butyrylamino}-4-[2-nitro-4-(3-trifluoromethyl-3H-diazirin-3-yl)-phenoxy]-butyric acid tert-butyl ester 

Relevant articles and documents

β-Phenylselenoalanine as a dehydroalanine precursor-efficient synthesis of alternariolide (AM-toxin I)

Alternariolide (AM-toxin) is synthesized in 44% overall yield from L-2-amino-5-(4-methoxyphenyl)pentanoic acid; D-β-phenylselenoalanine is used as the dehydroalanine precursor.

Synthesis of optically pure β-phenylselenoalanine through serine-β-lactone: A useful precursor of dehydroalanine

Optically pure L- and D-β-phenylselenoalanines (PhSeAla), useful precursors of dehydroalanine, were synthesized from L- and D-serine-β-lactone. Elimination reactions of the phenylseleno group to form the dehydroalanine were examined.