17891-78-0Relevant articles and documents
Formation of allylsilanes from Cl2[P(C6H11)3]2Ru=C(R)H and vinylsilanes - β-SIR'3 elimination from ruthenacyclobutanes as a terminating step in olefin cross-metathesis
Pietraszuk,Fischer
, p. 2463 - 2464 (2000)
Stoichiometric reactions of the Grubbs carbene complex [Cl2{P(C6H11)3}2Ru=C(Ph)H] with vinylsilanes, H2C=C(Si-Me(n)R(3-n))H (R = Ph, OEt; n = 1, 2, 3), afford metathesis products and allylsilanes formed by β-SiR3 elimination followed by reductive elimination; the formation of allylsilanes constitutes a terminating step in the Ru-catalysed cross-metathesis of olefins with methylsubstituted vinylsilanes.