178971-07-8Relevant articles and documents
Products of Reactions of Azido Derivatives of s-Triazine with Some O- and N-Nucleophiles
Azev, Yu. A.,Gusel'nikova, O. L.,Klyuev, N. A.,Shorshnev, S. V.,Rusinov, V. L.,Chupakhin, O. N.
, p. 1418 - 1424 (2007/10/03)
The mobility of the azido group in alkoxy derivatives of s-triazine in reactions with some O- and N-nucleophiles has been studied.Reactions of azidoalkoxy-s-triazines with ammonia gave products of substitution of both the azido and alkoxy groups.In reactions of azido-s-triazines with hydrazines, replacement of the azido group is accompanied by transformation of the triazine ring to give triazolylaminotetrazoles.Acid hydrolysis of diazidoalkoxy derivatives yields cyanuric acid as a result of substitution of both the azido and alkoxy groups.When diazidoalkoxy-s-triazines are heated in water in the absence of an acid, transformations of the triazine ring occurs with formation of bis(5-tetrazolyl)amine.