17902-83-9Relevant articles and documents
Titanocene-catalyzed formation of allylsilanes from allyl ethers and chlorosilanes
Nii, Shinsuke,Terao, Jun,Kambe, Nobuaki
, p. 1699 - 1702 (2004)
A new method for silylation of allyl ethers with chlorosilanes has been developed by the use of Cp2TiCl2 as a catalyst. This reaction proceeds efficiently at -20°C in THF using nBuMgCl. A plausible reaction pathway via allyltitanocene intermediate was proposed.