17911-16-9Relevant articles and documents
Steric Effects in the Catalytic Tandem Isomerization-Hydrosilylation Reaction
Prieto, Unai,Azpeitia, Susan,Sebastian, Eider San,Freixa, Zoraida,Garralda, María A.,Huertos, Miguel A.
, p. 1403 - 1409 (2021)
The selective synthesis of linear silanes from remote alkenes is reported. Four new silane-thioether bidentate proligands [SiMe2H(o-C6H4SR)] (R=iBu, pentyl, benzyl, neopentyl) have been synthesized and used to f
Carbonyl and olefin hydrosilylation mediated by an air-stable phosphorus(iii) dication under mild conditions
Andrews, Ryan J.,Chitnis, Saurabh S.,Stephan, Douglas W.
supporting information, p. 5599 - 5602 (2019/05/21)
The readily-accessible, air-stable Lewis acid [(terpy)PPh][B(C6F5)4]21 is shown to mediate the hydrosilylation of aldehydes, ketones, and olefins. The utility and mechanism of these hydrosilylations are considered.
Silicon(II) Cation Cp*Si:+ X-: A New Class of Efficient Catalysts in Organosilicon Chemistry
Fritz-Langhals, Elke
, p. 2369 - 2377 (2019/10/28)
The catalytic activity of the pentamethylcyclopentadienylsilicon(II) cation Cp*Si:+ was investigated. It was shown that Cp*Si:+ efficiently catalyzes reactions of technical relevance in organosilicon chemistry: Cp*Si:+ proved to be a very efficient nonmetallic catalyst for the hydrosilylation of olefins at low catalyst amounts of 0.01 mol % and for the Piers-Rubinsztajn reaction in order to make controlled silicone topologies. The thermal induction of hydrosilylation which is important for the manufacturing of silicone rubber can be achieved by small amounts of alkoxysilanes.
