17912-15-1

Basic information

• Product Name: 2H-Pyran, 2-cyclohexyltetrahydro-
• CAS NO: 17912-15-1
• Molecular Formula: C11H20O
• Molecular Weight: 168.279
• Mol File: 17912-15-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2H-Pyran, 2-cyclohexyltetrahydro-(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-Pyran, 2-cyclohexyltetrahydro-(17912-15-1)
• EPA Substance Registry System: 2H-Pyran, 2-cyclohexyltetrahydro-(17912-15-1)

Safety Data

• Hazardous Substances Data: 17912-15-1(Hazardous Substances Data)

Upstream product

• 55962-02-2 2-(2,4-Dichlorphenoxy)-3,4,5,6-tetrahydro-2H-pyran 
• 931-50-0 cyclohexylmagnesium bromide 
• 98078-14-9 5-cyclohexylidenepentan-1-ol 
• 57740-05-3 1-cyclohexylpentane-1,5-diol 
• 2043-61-0 cyclohexanecarbaldehyde 
• 562810-11-1 4-chloro-6-cyclohexyl-3,6-dihydro-2H-pyran 
• 110-87-2 3,4-dihydro-2H-pyran 

Relevant articles and documents

Iron(III)-catalyzed Prins-type cyclization using homopropargylic alcohol: A method for the synthesis of 2-alkyl-4-halo-5,6-dihydro-2H-pyrans

(Matrix presented) A new Prins-type cyclization between homopropargylic alcohol and aldehydes in the presence of FeX3 to obtain 2-alkyl-4-halo-5,6-dihydro2H-pyrans in good yield is described. Osmium-catalyzed cis dihydroxylation provided direct

Gold-catalysed cyclic ether formation from diols

Gold(I) and (III) salts have been found to be highly effective at the catalysis of ether formation from alcohols. Intramolecular ether formation of a 1,5-diol was also achieved, with a stereoselectivity that indicates that an SN1 mechanism predominates. In an attempt to form a seven-membered ring, a stable 14-membered dimer product was also formed. Attempts to control the diastereoselectivity of the reaction using a chiral anionic counterion did not give products with a high de.