17962-59-3Relevant articles and documents
A more critical role for silicon in the catalytic Staudinger amidation: Silanes as non-innocent reductants
Andrews, Keith G.,Denton, Ross M.
, p. 7982 - 7985 (2017)
A revised pathway for the catalytic Staudinger amidation reaction is presented that involves the intervention of in situ-generated silyl esters as the species responsible for amidation.
Designing a Cr-catalyst bearing redox non-innocent phenalenyl-based ligand towards hydrosilylative CO2functionalization
Chakraborty, Soumi,Das, Arpan,Ahmed, Jasimuddin,Barman, Sayani,Mandal, Swadhin K.
supporting information, p. 13788 - 13791 (2020/11/18)
Herein, we report the synthesis of a Cr(iii)-complex bearing a redox non-innocent phenalenyl-based ligand and its use as a catalyst for SET mediated hydrosilylative reduction of carbon dioxide towards formylation of primary amides under mild conditions. A
Phenylsilyl Chalcogenides, (Phenylsilyl)amines and Related Phosphonium (Phenylsilyl)methylides
Mitzel, Norbert W.,Schier, Annette,Beruda, Holger,Schmidbaur, Hubert
, p. 1053 - 1060 (2007/10/02)
The synthesis of 1,3-diphenyldisiloxane (1) by hydrolysis of chloro(phenyl)silane is optimized, 1,3-diphenyldisilthiane (2) is made available by the reaction of H2S with PhH2SiCl and triethylamine. 1,3-Diphenyldisilselenane (3) is prepared from K2Se and P
