179913-85-0Relevant articles and documents
Studies toward the synthesis of pinnatoxins: the spiroimine fragment
Stivala, Craig E.,Zakarian, Armen
, p. 6845 - 6848 (2007)
An enantioselective approach to the spiroimine fragment of pinnatoxins is described. The strategy is based on a recently developed diastereoselective Ireland-Claisen rearrangement to establish the challenging congested quaternary and tertiary stereocenters within the cyclohexene ring.