180071-29-8

Basic information

• Product Name: (CH₃)3SnSO₃C(C₆H₉)CHSO₃Sn(CH₃)3
• CAS NO: 180071-29-8
• Molecular Weight: 593.925
• Mol File: 180071-29-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (CH₃)3SnSO₃C(C₆H₉)CHSO₃Sn(CH₃)3(CAS DataBase Reference)
• NIST Chemistry Reference: (CH₃)3SnSO₃C(C₆H₉)CHSO₃Sn(CH₃)3(180071-29-8)
• EPA Substance Registry System: (CH₃)3SnSO₃C(C₆H₉)CHSO₃Sn(CH₃)3(180071-29-8)

Safety Data

• Hazardous Substances Data: 180071-29-8(Hazardous Substances Data)

Upstream product

• 180070-46-6 ((CH₃)3Sn)C(C₆H₉)CH(Sn(CH₃)3) 
• 7446-11-9 sulfur trioxide 

Relevant articles and documents

Tin for organic synthesis. Part 15 : The use of 1,2-bis(trimethylstannyl) -1-alkenes in electrophilic destannylation reactions

Z-1,2-Bis(trimethylstannyl)-1-alkenes show different types of reaction behaviour towards various electrophiles. p-Tolysulphonyliso-cyanate forms five-membered tin-nitrogen-containing heterocycles. 1,1-Dichloromethylmethyl ether reacts with carbofunctionalised distannylalkenes to yield α,β-unsaturated aldehydes, which are useful tools for the synthesis of further substituted vinylstannanes. Z-1,2-Bis(trimethylstannyl)- 1-alkenes containing heteroatoms such as O or N undergo only protodestannylation with this electrophile. The reaction of Z-1,2-bis (trimethylstannyl)-1-alkenes with trimethylsilyl chlorosulphonate followed by hydrolysis with aqueous NaHCO3 provides the corresponding sodium sulphonates. SO2 and SO3 undergo insertion into both tin-carbon bonds in an ipso- and stereospecific manner to form bis-sulphinic- or bis-sulphonic bis(trialkylstannyl) esters.