180404-53-9Relevant articles and documents
Influence of intramolecular hydrogen-bonding on the conformation of 3-deoxy-3-thioureido sugars
Fernandez, Jose M. Garcia,Mellet, Carmen Ortiz,Blanco, Jose L. Jimenez,Fuentes, Jose,Dianez, Maria Jesus,et al.
, p. 55 - 66 (1996)
3-Deoxy-3-thioureido derivatives of 1,2:5,6-di-O-isopropylidene-α-D-allofuranose and 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose were prepared, and their conformational properties in chloroform-d solutions were studied by temperature variable 1H NMR spe
Tautomeric rearrangement of 3-deoxy-3-thioureidoaldoses: a novel synthetic route to carbohydrate mimics having a cyclic thiourea structure
Blanco, Jose L. Jimenez,Mellet, Carmen Ortiz,Fuentes, Jose,Fernandez, Jose M. Garcia
, p. 2077 - 2078 (2007/10/03)
Cyclic thiourea glycomimetics structurally realted to 3-deoxy-2-nonulosonic acids (KDNs) and 1,5-dideoxy-1,5-iminooctitols (azaoctitols) have been prepared by tautomeric rearrangement of 3-deoxy-3-thioureidoaldohexoses; the conformational properties of these compounds are governed by stereoelectronic requirements, mainly the anomeric effect.