18052-88-5

Basic information

• Product Name: Silane, (2-methylphenyl)phenyl-
• CAS NO: 18052-88-5
• Molecular Formula: C13H14Si
• Molecular Weight: 198.34
• Mol File: 18052-88-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Silane, (2-methylphenyl)phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, (2-methylphenyl)phenyl-(18052-88-5)
• EPA Substance Registry System: Silane, (2-methylphenyl)phenyl-(18052-88-5)

Safety Data

• Hazardous Substances Data: 18052-88-5(Hazardous Substances Data)

Upstream product

• 95-46-5 2-methylphenyl bromide 
• 694-53-1 phenylsilane 
• 615-37-2 ortho-methylphenyl iodide 
• 932-31-0 ortho-tolylmagnesium bromide 

Downstream Products

• 201216-21-9 phenyl-m-tolyl-o-tolyl-silane 
• 18751-19-4 [3-(2-chloro-phenyl)-propyl]-phenyl-o-tolyl-silane 
• 18858-67-8 (4-phenoxy-phenyl)-phenyl-o-tolyl-silane 
• 18870-37-6 phenyl-m-tolyl-o-tolyl-p-tolyl-silane 
• 18758-55-9 methyl-(4-phenoxy-phenyl)-phenyl-o-tolyl-silane 
• 18834-12-3 (4-phenoxy-phenyl)-phenyl-o-tolyl-p-tolyl-silane 

Relevant articles and documents

Silylation of Aryl Halides with Monoorganosilanes Activated by Lithium Alkoxide

Lithium alkoxide activates a monoorganosilane to generate a transient LiH/alkoxysilane complex, which quickly reacts with aryl and alkenyl halides at 25 °C to deliver a diorganosilane product. Experimental and theoretical studies suggest that the reaction includes nucleophilic attack of LiH on the halogen atom of the organic halide to generate a transient organolithium/alkoxysilane intermediate, which undergoes quick carbon-silicon bond formation within the complex.