18064-78-3Relevant articles and documents
Diselenide-Mediated Catalytic Functionalization of Hydrophosphoryl Compounds
Handoko,Benslimane, Zacharia,Arora, Paramjit S.
, p. 5811 - 5816 (2020/07/27)
We report a diaryldiselenide catalyst for cross-dehydrogenative nucleophilic functionalization of hydrophosphoryl compounds. The proposed organocatalytic cycle closely resembles the mechanism of the Atherton-Todd reaction, with the catalyst serving as a recyclable analogue of the halogenating agent employed in the named reaction. Phosphorus and selenium NMR studies reveal the existence of a P-Se bond intermediate, and structural analyses indicate a stereospecific reaction.
Reactions of Monocyclopentadienyl Complexes of Molybdenum and Tungsten with Derivatives of Phenols and Pentafluorobenzeneselenol
Davidson, Jack L.,Holz, Birgit,Leverd, Pascal C.,Lindsell, W. Edward,Simpson, Nigel J.
, p. 3527 - 3532 (2007/10/02)
Reactions of (cp = η5-C5H5) with thallium salts Tl(OR) (R = aryl) in tetrahydrofuran did not produce simple substitution products but afforded reduced species 2, oxidised species or the thalliu