180713-44-4

Basic information

• Product Name: Propanoic acid, 2,2-dimethyl-, (2-formylphenyl)methyl ester
• CAS NO: 180713-44-4
• Molecular Formula: C13H16O3
• Molecular Weight: 220.268
• Mol File: 180713-44-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Propanoic acid, 2,2-dimethyl-, (2-formylphenyl)methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propanoic acid, 2,2-dimethyl-, (2-formylphenyl)methyl ester(180713-44-4)
• EPA Substance Registry System: Propanoic acid, 2,2-dimethyl-, (2-formylphenyl)methyl ester(180713-44-4)

Safety Data

• Hazardous Substances Data: 180713-44-4(Hazardous Substances Data)

Upstream product

• 3282-30-2 pivaloyl chloride 
• 341519-79-7 2-hydroxymethylbenzyl pivalate 
• 59868-79-0 1,3-dihydroisobenzofuran-1-ol 
• 138459-91-3 3-pivaloyl-1,3-thiazolidine-2-thione 

Downstream Products

• 341519-82-2 2,2-dimethyl-propionic acid 2-{4-(tert-butyl-dimethyl-silanyl)-1-[3-hydroxy-3-(4-nitro-phenyl)-3-phenyl-prop-1-ynyl]-but-1-en-3-ynyl}-benzyl ester 
• 341519-91-3 2,2-dimethyl-propionic acid 2-{4-(tert-butyl-dimethyl-silanyl)-1-[3-methoxy-3-(4-nitro-phenyl)-3-phenyl-prop-1-ynyl]-but-1-en-3-ynyl}-benzyl ester 
• 341519-85-5 2-{4-(tert-butyl-dimethyl-silanyl)-1-[3-methoxy-3-(4-nitro-phenyl)-3-phenyl-prop-1-ynyl]-but-1-en-3-ynyl}-benzoic acid 
• 341519-83-3 (2-{4-(tert-butyl-dimethyl-silanyl)-1-[3-methoxy-3-(4-nitro-phenyl)-3-phenyl-prop-1-ynyl]-but-1-en-3-ynyl}-phenyl)-methanol 
• 341519-84-4 2-{4-(tert-butyl-dimethyl-silanyl)-1-[3-methoxy-3-(4-nitro-phenyl)-3-phenyl-prop-1-ynyl]-but-1-en-3-ynyl}-benzaldehyde 
• 341519-86-6 2-{(Z)-1-[3-Methoxy-3-(4-nitro-phenyl)-3-phenyl-prop-1-ynyl]-but-1-en-3-ynyl}-benzoic acid 
• 341519-88-8 2-{(Z)-1-[3-Methoxy-3-(4-methoxy-phenyl)-3-phenyl-prop-1-ynyl]-but-1-en-3-ynyl}-benzoic acid 
• 341519-81-1 2,2-dimethyl-propionic acid 2-[4-(tert-butyl-dimethyl-silanyl)-1-ethynyl-1-hydroxy-but-3-ynyl]-benzyl ester 
• 341519-90-2 2,2-dimethyl-propionic acid 2-[4-(tert-butyl-dimethyl-silanyl)-1-ethynyl-but-1-en-3-ynyl]-benzyl ester 

Relevant articles and documents

Developments of enediyne model compounds generating biradicals with an enhanced radical character - Regulation of triggering devices

Development of enediyne model compounds generating biradicals with an enhanced radical character is described. These model compounds generate enyne-allenes under mild acidic conditions and the resulting biradicals showed potent DNA cleaving abilities.

Twisted amides as selective acylating agents for hydroxyl groups under neutral conditions: Models for activated peptides during enzymatic acyl transfer reaction

The highly twisted amide 2 served as a selective acylating agent for diols under neutral conditions. The reaction of primary-secondary diols with 2 led to the corresponding primary alkyl monopivalates. For diols containing alcoholic and phenolic hydroxyl groups, alcoholic hydroxyl groups were selectively acylated under neutral conditions, whereas, the opposite selectivity was observed under basic conditions, similar to the cases using acyl halides or acid anhydrides. Although 1 and 3 were unreactive to alcohols, 5-10 having substituent groups at C-4 were reactive to alcohols to give the corresponding acetates or benzoates.