180890-43-1

Basic information

• Product Name: 3,5-Cyclohexadiene-1,2-dione, 4-(hydroxymethyl)-
• CAS NO: 180890-43-1
• Molecular Formula: C7H6O3
• Molecular Weight: 138.123
• Mol File: 180890-43-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3,5-Cyclohexadiene-1,2-dione, 4-(hydroxymethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-Cyclohexadiene-1,2-dione, 4-(hydroxymethyl)-(180890-43-1)
• EPA Substance Registry System: 3,5-Cyclohexadiene-1,2-dione, 4-(hydroxymethyl)-(180890-43-1)

Safety Data

• Hazardous Substances Data: 180890-43-1(Hazardous Substances Data)

Upstream product

• 620-24-6 3-Hydroxybenzyl alcohol 
• 623-05-2 (4-hydroxyphenyl)methanol 
• 7382-59-4 guaiacylglycerol-β-guaiacyl ether 
• 4383-06-6 3-hydroxy-4-methoxybenzyl alcohol 
• 498-00-0 4-hydroxymethyl-2-methoxyphenol 

Downstream Products

• 3897-89-0 4-(hydroxymethyl)benzene-1,2-diol 

Relevant articles and documents

Chemo-selective oxidation of hydroxybenzyl alcohols with IBX in the presence of hemicucurbit[6]uril

The chemo-selective oxidation of bifunctional substrates via a supramolecular strategy has been achieved. IBX (o-iodoxybenzoic acid) oxidations of hydroxybenzyl alcohols produce the corresponding aldehyde and o-quinones, while the presence of HemiQ[6] can restrain the IBX oxidation of phenolic hydroxyl groups to afford the aldehyde product. The conversion and reaction rate are greatly affected by the structures of substrates, and the stereo effect and electronic effect play very important roles in the selective oxidation system. Various spectroscopies, including 1H NMR (proton nuclear magnetic resonance), IR (infrared), and UV-vis (ultra violet-visible) have been employed to confirm the host-guest interaction of HemiQ[6] with hydroxybenzyl alcohols.

ANODIC OXIDATION OF 2-METHOXYPHENOLS IN ACETONITRILE

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