180962-68-9

Basic information

• Product Name: ((E)-7-Bromo-3-ethoxymethoxy-hept-1-ene-1-sulfonyl)-benzene
• Synonyms: ((E)-7-Bromo-3-ethoxymethoxy-hept-1-ene-1-sulfonyl)-benzene
• CAS NO: 180962-68-9
• Molecular Weight: 391.326
• Mol File: 180962-68-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((E)-7-Bromo-3-ethoxymethoxy-hept-1-ene-1-sulfonyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: ((E)-7-Bromo-3-ethoxymethoxy-hept-1-ene-1-sulfonyl)-benzene(180962-68-9)
• EPA Substance Registry System: ((E)-7-Bromo-3-ethoxymethoxy-hept-1-ene-1-sulfonyl)-benzene(180962-68-9)

Safety Data

• Hazardous Substances Data: 180962-68-9(Hazardous Substances Data)

Upstream product

• 57978-00-4 6-bromohexanal 
• 180962-66-7 (E)-1-Benzenesulfonyl-7-bromo-hept-1-en-3-ol 
• 3188-13-4 ethyl chloromethyl ether 

Relevant articles and documents

γ-Oxygenated-α,β-unsaturated sulfones in radical cyclizations and cascade processes

A wide variety of radical precursors having the structure of γ-oxygenated-α,β-unsaturated sulfone (substrates 1-4) have been prepared. Both 5-hexenyl and 6-heptenyl radicals, generated by reaction of substrates 1-4 with Bu3SnH/AIBN, underwent an efficient cyclization via intramolecular addition to the vinyl sulfone moiety. By introduction of a double bond joined to the oxygen at γ-position, a cascade process based on two sequential radical cyclizations took place, affording highly substituted 2-oxa[3.3.0] or 9-oxa[4.3.0] bicyclic compounds.