18105-49-2Relevant articles and documents
An air-stable, Zn2+-based catalyst for hydrosilylation of alkenes and alkynes
Dobrovetsky, Roman,Groutchik, Kristina,Jaiswal, Kuldeep
supporting information, p. 5544 - 5550 (2021/07/02)
Hydrosilylation of C-C double and C-C triple bonds is one of the most widely used processes in organosilicon chemistry, mostly catalyzed by Pt-based complexes. We report here the synthesis of an air-stable dicationic Zn2+-based complex in a hem
Silicon(II) Cation Cp*Si:+ X-: A New Class of Efficient Catalysts in Organosilicon Chemistry
Fritz-Langhals, Elke
, p. 2369 - 2377 (2019/10/28)
The catalytic activity of the pentamethylcyclopentadienylsilicon(II) cation Cp*Si:+ was investigated. It was shown that Cp*Si:+ efficiently catalyzes reactions of technical relevance in organosilicon chemistry: Cp*Si:+ proved to be a very efficient nonmetallic catalyst for the hydrosilylation of olefins at low catalyst amounts of 0.01 mol % and for the Piers-Rubinsztajn reaction in order to make controlled silicone topologies. The thermal induction of hydrosilylation which is important for the manufacturing of silicone rubber can be achieved by small amounts of alkoxysilanes.
The highly lewis acidic dicationic phosphonium salt: [(SIMes)PFPh 2][B(C6F5)4]2
Holthausen, Michael H.,Mehta, Meera,Stephan, Douglas W.
supporting information, p. 6538 - 6541 (2014/06/24)
The dicationic imidazolium-phosphonium salt [(SIMes)PFPh 2][B(C6F5)4]2 has been prepared and shown to exhibit remarkable Lewis acidity in stoichiometric reactions and acting as an effective Lewis acid catalyst for the hydrodefluorination of fluoroalkanes and the hydrosilylation of olefins.
