181589-81-1

Basic information

• Product Name: (C₅H₅)Fe(C₅H₄CONHCH(CH₂C₆H₅)COOCH₃)
• CAS NO: 181589-81-1
• Molecular Weight: 391.25
• Mol File: 181589-81-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (C₅H₅)Fe(C₅H₄CONHCH(CH₂C₆H₅)COOCH₃)(CAS DataBase Reference)
• NIST Chemistry Reference: (C₅H₅)Fe(C₅H₄CONHCH(CH₂C₆H₅)COOCH₃)(181589-81-1)
• EPA Substance Registry System: (C₅H₅)Fe(C₅H₄CONHCH(CH₂C₆H₅)COOCH₃)(181589-81-1)

Safety Data

• Hazardous Substances Data: 181589-81-1(Hazardous Substances Data)

Upstream product

• 1271-42-7 ferrocenecarboxylic acid 
• 5619-07-8 methyl 2-amino-3-phenylpropanoate hydrochloride 

Relevant articles and documents

Metal complexes of biologically important ligands, CXIV ferrocenyl-oxazolones as N and C donors in Pd(II), Pt(II) and Ir(III) complexes and ferrocenoyl-dipeptides

2-Ferrocenyl-4R-5(4H)-oxazolones 1-5 were obtained from N-ferrocenoyl-α-amino acids and function as N donors in dichloro-phosphine-palladium(II) and platinum(II) complexes 6-18. The reaction of ferrocenyl-oxazolone and ferrocenyl-bis(oxazolone) with [Cp*IrCl2]2 afforded trimetallic and pentametallic complexes 19 and 20 with a C,N bridging oxazolone. Ring opening of the ferrocenyl-oxazolones 1, 2 and 4 with α-amino acid esters gave N-ferrocenoyl-dipeptide esters 21-26. In the ferrocene bis(dipeptides) the two peptide esters are aligned parallel by hydrogen bonding. The structures of 6 and 19 were determined by X-ray diffraction.