181784-19-0

Basic information

• Product Name: InI₃(P(C₆H₅)3)*InI₃(P(C₆H₅)3)2
• CAS NO: 181784-19-0
• Molecular Weight: 1777.94
• Mol File: 181784-19-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: InI₃(P(C₆H₅)3)*InI₃(P(C₆H₅)3)2(CAS DataBase Reference)
• NIST Chemistry Reference: InI₃(P(C₆H₅)3)*InI₃(P(C₆H₅)3)2(181784-19-0)
• EPA Substance Registry System: InI₃(P(C₆H₅)3)*InI₃(P(C₆H₅)3)2(181784-19-0)

Safety Data

• Hazardous Substances Data: 181784-19-0(Hazardous Substances Data)

Upstream product

• 7440-74-6 indium 
• 6396-07-2 triphenylphosphine diiodide 

Downstream Products

• 15810-57-8 indium(III) iodide, triphenylphosphine adduct 

Relevant articles and documents

Reaction of indium metal with R3PI2 (R = Ph, Pri, Prn); structural characterisation of the novel 'subvalent' indium(II) complex In2I4(PPrn 3)2 which contains an In-In bond, the four- and five- coordinate indium(III) complex InI3(PPh3)2 ·InI3

Reaction of R3PI2 (R = Ph, Prn, Pri) with indium metal powder produces a variety of novel indium metal complexes: where R = Ph, the four- and five-coordinate metal(III) complex InI3(PPh3)2·InI3(PPh 3) results; where R = Prn, the 'subvalent' indium(II) complex In2I4(PPrn3)2 is formed, the first example of an indium tertiary phosphine complex containing an indium-indium bond; whereas for R = Pri, the monomeric tetrahedral indium(III) complex InI3(PPri3) results; these complexes illustrate the subtle effect of the organic substituents on the phosphorus atom for the reaction of R3PI2 with indium metal powder and the novel indium complexes which are available.