182-01-4

Basic information

• Product Name: 7,8,15,16,23,24-hexaoxatrispiro[5.2.5.2.5.2]tetracosane
• Synonyms: 7,8,15,16,23,24-hexaoxatrispiro[5.2.5.2.5.2]tetracosane;2,3,5,6,8,9-Hexaoxatrisprio[cyclononane-1,1':4,1'':7,1'''-tricyclohexane];3,3-Pentamethylene-6,6-pentamethylene-9,9-pentamethylene-1,2,4,5,7,8-hexaoxacyclononane;7,8,15,16,23,24-Hexaoxatrisprio [5.2.5:2.5:2]tetracosane;7,8,15,16,23,24-Hexaoxatrisprio[5.2.5:2.5.2]tetracosane;Trisprio[1,2,4,5,7,8-hexaoxacyclononane-3,1':6,1'':9,1'''-tricyclohexane];7,8,15,16,23,24-hexaoxatrispiro[5.2.5^{9}.2.5^{17}.2^{6}]tetracosane
• CAS NO: 182-01-4
• Molecular Formula: C₁₈H₃₀O₆
• Molecular Weight: 344.44308
• EINECS: 205-872-8
• Mol File: 182-01-4.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 417°Cat760mmHg
• Flash Point: 165.6°C
• Appearance: /
• Density: 1.18g/cm³
• Vapor Pressure: 8.88E-07mmHg at 25°C
• Refractive Index: 1.521
• CAS DataBase Reference: 7,8,15,16,23,24-hexaoxatrispiro[5.2.5.2.5.2]tetracosane(CAS DataBase Reference)
• NIST Chemistry Reference: 7,8,15,16,23,24-hexaoxatrispiro[5.2.5.2.5.2]tetracosane(182-01-4)
• EPA Substance Registry System: 7,8,15,16,23,24-hexaoxatrispiro[5.2.5.2.5.2]tetracosane(182-01-4)

Safety Data

• Hazardous Substances Data: 182-01-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C18H30O6/c1-4-10-16(11-5-1)19-21-17(12-6-2-7-13-17)23-24-18(22-20-16)14-8-3-9-15-18/h1-15H2

Upstream product

• 79-21-0 peracetic acid 
• 108-94-1 cyclohexanone 
• 2699-12-9 bis-(1-hydroperoxycyclohexyl)peroxide 
• 74897-52-2 1-(1-hydroxycyclohexyldioxy)-1-(1-hydroperoxycyclohexyldioxy)cyclohexane 
• 933-40-4 cycloxexanone dimethyl ketal 
• 931-57-7 1-methoxy-cyclohex-1-ene 
• 78-18-2 1-hydroxycyclohexyl 1-hydroperoxycyclohexyl peroxide 
• 2407-94-5 1,1'-dihydroxycyclohexyl peroxide 
• 202197-70-4 methyl 2-(4-oxopiperidin-1-yl)acetate 
• 2699-11-8 1,1-dihydroperoxycyclohexane 

Downstream Products

• 295-48-7 cyclopentadecane 
• 502-44-3 hexahydro-2H-oxepin-2-one 
• 109-29-5 15-hexadecanolide 
• 108-94-1 cyclohexanone 

Relevant articles and documents

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Flow Chemistry under Extreme Conditions: Synthesis of Macrocycles with Musklike Olfactoric Properties

Starting from small cyclic ketones, continuous flow synthesis is used to produce medium-sized rings and macrocycles that are relevant for the fragrance industry. Triperoxides are important intermediates in this process and are pyrolyzed at temperatures above 250 °C. The synthesis is carried out in two continuously operated flow reactors connected by a membrane-operated separator. The practicality of flow chemistry is impressively demonstrated in this work by the use of hazardous reagent mixtures (30% H2O2, 65% HNO3) and the pyrolysis of no less problematic peroxides. All new macrocycles were tested for their olfactory properties in relation to musk.

Unique trifurcated hydrogen bonding in a pseudopolymorph of tricyclohexane triperoxide (TCTP) and its thermal studies

Tricyclohexane triperoxide (TCTP) was synthesized as a main by-product of tetraoxane synthesis and was characterized by spectroscopic techniques viz. 1H NMR, 13C NMR, FT-IR and Raman. The single crystal X-ray structure revealed the inclusion of solvent in 1:1 stoichiometric ratio involving a unique trifurcated C(sp3)-H...O hydrogen bonding imparting remarkable symmetry to the molecule. The thermal stability of single crystal was determined by TG-DTA and DSC.