1820-84-4Relevant articles and documents
A Chromium Hydroxide/MIL-101(Cr) MOF Composite Catalyst and Its Use for the Selective Isomerization of Glucose to Fructose
Guo, Qiang,Ren, Limin,Kumar, Prashant,Cybulskis, Viktor J.,Mkhoyan, K. Andre,Davis, Mark E.,Tsapatsis, Michael
supporting information, p. 4926 - 4930 (2018/03/27)
A metal–organic framework (MOF)-based catalyst, chromium hydroxide/MIL-101(Cr), was prepared by a one-pot synthesis method. The combination of chromium hydroxide particles on and within Lewis acidic MIL-101 accomplishes highly selective conversion of gluc
METHOD OF PREPARING FURFURAL COMPOUNDS
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Paragraph 0064, (2014/05/20)
Provided is a two-step method of producing a compound of chemical formula 1 in the presence of an alcohol solvent and a Group 3B metal catalyst or a salt thereof, comprising a first step comprising alkylation or isomerization of an aldohexose-containing substrate to obtain an intermediate, and a second step comprising dehydration of the intermediate to produce a compound of chemical formula 1. Preferably, additional solvent and/or catalyst are not added in the second step.
Conversion of fructose into 5-hydroxymethylfurfural (HMF) and its derivatives promoted by inorganic salt in alcohol
Liu, Jitian,Tang, Yu,Wu, Kaigui,Bi, Caifeng,Cui, Qiu
experimental part, p. 20 - 24 (2012/03/22)
The conversion of d-fructose to 5-hydroxymethylfurfural (HMF) on a 1 mmol scale was achieved in good yield (68%) using NH4Cl as catalyst in isopropanol at 120 °C. About 3% of 5-i-propoxymethylfurfural was formed. The reaction in ethanol at 100 °C on a 10 g scale gave a total yield of HMF and 5-ethoxymethylfurfural of 42%. No mineral acid such as H2SO 4 and HCl are required.