182002-72-8

Basic information

• Product Name: [(η(5)-C5Me5)RhCl(1,2-bis(bis(pentafluorophenyl)phosphino)ethane)]BF4
• CAS NO: 182002-72-8
• Molecular Weight: 1118.63
• Mol File: 182002-72-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(η(5)-C5Me5)RhCl(1,2-bis(bis(pentafluorophenyl)phosphino)ethane)]BF4(CAS DataBase Reference)
• NIST Chemistry Reference: [(η(5)-C5Me5)RhCl(1,2-bis(bis(pentafluorophenyl)phosphino)ethane)]BF4(182002-72-8)
• EPA Substance Registry System: [(η(5)-C5Me5)RhCl(1,2-bis(bis(pentafluorophenyl)phosphino)ethane)]BF4(182002-72-8)

Safety Data

• Hazardous Substances Data: 182002-72-8(Hazardous Substances Data)

Upstream product

• 13826-83-0 ammonium tetrafluroborate 
• 76858-94-1 1,2-bis(di(pentafluorophenyl)phosphino)ethane 

Downstream Products

• 163237-62-5 [(η(5)-C5Me3[CH2C6F4P(C6F5)2CH2]2-1,3)RhCl](1+) 
• 182002-80-8 [(η(5)-C5Me4(CH2C6F4P(C6F5)CH2CH2P(C6F5)2))RhCl](1+) 
• 235103-35-2 [(η(5)-C5Me5)RhCl(1,2-bis(bis(pentafluorophenyl)phosphino)ethane)](+).Cl(-) 

Relevant articles and documents

Carbon-fluorine and -hydrogen bond activation and carbon-carbon bond formation in η5-pentamethylcyclopentadienyl-rhodium and -iridium phosphine complexes; crystal structures of

The reaction between [{M(η5-C5Me5)Cl(μ-Cl)}2] (M = Rh or Ir) and (C6F5)2PCH2CH2P(C 6F5)2 (dfppe) in refluxing benzene yielded the cationic species [M{η5-C5Me3[CH2C 6F4P(C6F5)CH2] 2-1,3}Cl]+ in which two C-F and two C-H bonds have been cleaved and two C-C bonds formed; HF is also produced. The complexes [M(η5-C5Me5)Cl(dfppe)]+BF 4- (M = Rh or Ir), which have not undergone C-F bond activation, were formed by treatment of [{M(η5-C5Me5)Cl(μ-Cl)}2] with NH4BF4. and dfppe, and have been structurally characterized by X-ray crystallography. Activation of the C-F bonds in these complexes is induced by thermolysis in refluxing ethanol. The reaction between [{M(η5-C5Me5)Cl(μ-Cl)}2] (M = Rh or Ir) and dfppe in refluxing ethanol yielded a mixture of the cations [M(η5-C5Me5)Cl(dfppe)]+, [M{η5-C5Me3[CH2C 6F4P(C6F5)CH2] 2-1,3}Cl]+ and, where M = Rh, the singly C-F bond-activated species [Rh{η5-C5Me4CH2C 6F4P(C6F5)CH2CH 2P(C6F5)2}Cl]+.