182014-79-5

Basic information

• Product Name: 2-acetoxy-4,5-dimethoxybenzaldehyde
• Synonyms: 2-acetoxy-4,5-dimethoxybenzaldehyde
• CAS NO: 182014-79-5
• Molecular Weight: 224.213
• Mol File: 182014-79-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-acetoxy-4,5-dimethoxybenzaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: 2-acetoxy-4,5-dimethoxybenzaldehyde(182014-79-5)
• EPA Substance Registry System: 2-acetoxy-4,5-dimethoxybenzaldehyde(182014-79-5)

Safety Data

• Hazardous Substances Data: 182014-79-5(Hazardous Substances Data)

Upstream product

• 14382-91-3 2-hydroxy-4,5-dimethoxybenzaldehyde 
• 108-24-7 acetic anhydride 
• 4460-86-0 asaraldehyde 

Downstream Products

• 120-08-1 Scoparone 
• 305-01-1 aesculetin 
• 5722-93-0 2-hydroxy-4,5-dimethoxybenzoic acid 
• 854660-72-3 2-acetoxy-4,5-dimethoxy-benzoic acid 

Relevant articles and documents

Anchimerically Assisted Selective Cleavage of Acid-Labile Aryl Alkyl Ethers by Aluminum Triiodide and N, N-Dimethylformamide Dimethyl Acetal

Aluminum triiodide is harnessed by N,N-dimethylformamide dimethyl acetal (DMF-DMA) for the selective cleavage of ethers via neighboring group participation. Various acid-labile functional groups, including carboxylate, allyl, tert-butyldimethylsilyl (TBS), and tert-butoxycarbonyl (Boc), suffer the conditions intact. The method offers an efficient approach to cleaving catechol monoalkyl ethers and to uncovering phenols from acetal-type protecting groups such as methoxymethyl (MOM), methoxyethoxymethyl (MEM), and tetrahydropyranyl (THP) chemoselectively.