182065-79-8Relevant articles and documents
Opening and hydrogenation of dinaphtho[2,1-b:1′,2′-d]thiophene (DNT) by soluble rhodium and iridium complexes. Homogeneous hydrogenolysis of DNT to 1,1′-binaphthalene-2-thiol by rhodium catalysis
Bianchini, Claudio,Fabbri, Davide,Gladiali, Serafino,Meli, Andrea,Pohl, Wolfgang,Vizza, Francesco
, p. 4604 - 4611 (2008/10/08)
The fragment [(triphos)IrH], generated in situ by thermolysis of (triphos)Ir(H)2(C2H5) in THF, reacts with dinaphtho[2,1-b:1′,2′-d]thiophene (DNT) at temperatures higher than 100 °C to give a temperature-invariant 3:2 mixt