182319-00-2Relevant articles and documents
A spectroscopic study of some substitued tris(diimine) complexes of ruthenium(II) and their reduction products
Donohoe, R. J.,Tait, C. D.,Dearmond, M. K.,Wertz, D. W.
, p. 233 - 240 (1986)
The electronic absorption and resonance Raman spectra of the parent and one- to six-electron reduction products of tris(5,5'-bis(ethoxycarbonyl)-2,2'-bipyridine)ruthenium(II) and tris(5,5'-bis(phenyl)-2,2'-bipyridine)rythenium(II) indicate that the redox
Mechanistic insights into the potassium: Tert -butoxide-mediated synthesis of N-heterobiaryls
Stephens, David E.,Lakey-Beitia, Johant,Burch, Jessica E.,Arman, Hadi D.,Larionov, Oleg V.
supporting information, p. 9945 - 9948 (2016/08/11)
We report herein that symmetrical and non-symmetrical N-heterobiaryls are produced by a potassium tert-butoxide-mediated dimerization of heterocyclic N-oxides. The reaction is scalable and transition metal-free, and can be carried out under thermal and microwave conditions. Preliminary mechanistic studies point to the involvement of radical anionic intermediates arising from the N-oxide substrates and potassium tert-butoxide.