18232-27-4

Basic information

• Product Name: Benzene, (3-ethoxy-2-propenyl)-
• CAS NO: 18232-27-4
• Molecular Formula: C11H14O
• Molecular Weight: 162.232
• Mol File: 18232-27-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Benzene, (3-ethoxy-2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (3-ethoxy-2-propenyl)-(18232-27-4)
• EPA Substance Registry System: Benzene, (3-ethoxy-2-propenyl)-(18232-27-4)

Safety Data

• Hazardous Substances Data: 18232-27-4(Hazardous Substances Data)

Upstream product

• 931-49-7 1-ethenylcyclohexene 
• 100-39-0 benzyl bromide 
• 3054-95-3 acrylaldehyde diethyl acetal 
• 108-86-1 bromobenzene 
• 18229-79-3 3-Cyclohexen-⁽¹⁾-yl-propin-⁽²⁾-al-⁽¹⁾-diethylacetal 
• 1889-20-9 n-butylmagnesium iodide 
• 115476-82-9 (E)-1-benzyl-2-ethoxy-1-(p-tolylsulfonyl)ethylene 

Downstream Products

• 104-53-0 3-phenyl-propionaldehyde 
• 115476-83-0 2-bromo-3-phenylpropionaldehyde diethyl acetal 
• 6956-37-2 (3,3-diethoxypropyl)benzene 
• 129601-06-5 (2-Chloro-3-ethoxy-2-fluoro-cyclopropylmethyl)-benzene 

Relevant articles and documents

-

-

Nickel-Catalyzed Arylation of Acrolein Diethyl Acetal: A Substitute to the 1,4-Addition of Arylhalides to Acrolein

(Equation presented) In the presence of catalytic amount of NIBr 2 as catalyst precursor, organic halides are reductively coupled at 70°C with acrolein diethyl acetal to give (Z)- and (E)-enolethers by allylic deplacement of an alkoxy group. Subsequent hydrolysis affords β-arylated aldehydes.

CONFIGURATIONAL PROPERTIES AND CHEMICAL REACTIVITY OF MONO AND DIANIONS DERIVED FROM ARYL 2-ALKOXYVINYL SULFONES

E-2-Alkoxy-1-arylsulfonylethenes are regio and stereospecifically lithiated at C-1 and the resulting species react efficiently with a variety of electrophiles to give synthetically useful products.