182355-73-3Relevant articles and documents
Stereocontrolled Synthesis of α-C-Galactosamine Derivatives via Chelation-Controlled C-Glycosylation
Urban, Dominique,Skrydstrup, Troels,Beau, Jean-Marie
, p. 2507 - 2516 (2007/10/03)
The samarium diiodide-promoted reduction of 2-deoxy-2-acetamidogalactosyl pyridyl sulfone α-5 with ketones or aldehydes under Barbier conditions led unexpectedly to the stereoselective synthesis of α-C-galactosamine derivatives in good yields. With carbon