182690-97-7

Basic information

• Product Name: 2,2-dimethyl-5-(trifluoromethanesulfonyloxy)methyl-1,3-dioxane
• Synonyms: 2,2-dimethyl-5-(trifluoromethanesulfonyloxy)methyl-1,3-dioxane
• CAS NO: 182690-97-7
• Molecular Weight: 278.249
• Mol File: 182690-97-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,2-dimethyl-5-(trifluoromethanesulfonyloxy)methyl-1,3-dioxane(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-dimethyl-5-(trifluoromethanesulfonyloxy)methyl-1,3-dioxane(182690-97-7)
• EPA Substance Registry System: 2,2-dimethyl-5-(trifluoromethanesulfonyloxy)methyl-1,3-dioxane(182690-97-7)

Safety Data

• Hazardous Substances Data: 182690-97-7(Hazardous Substances Data)

Upstream product

• 4728-12-5 2,2-dimethyl-5-hydroxymethyl-1,3-dioxane 
• 358-23-6 trifluoromethylsulfonic anhydride 

Relevant articles and documents

Lipase-catalyzed enantioselective acylation of prochiral 2-(ω)-phosphono)alkyl-1,3-propanediols: Application to the enantioselective synthesis of ω-phosphono-α-amino acids

Lipase PS catalyzed acetylation of prochiral 2-(ω-phosphono)alkyl-1,3-propanediols 1a-c was found to proceed with high enantioselectivity. The applications of phosphonic chirons 2a-c thus obtained were illustrated by the stereocontrolled synthesis of ω-phosphono-α-amino acids such as L-AP-3, L-AP-4, and N-Boc-L-F2Pab(OEt)2-OH.