18271-18-6Relevant articles and documents
Modular Two-Step Access to π-Extended Naphthyridine Systems—Potent Building Blocks for Organic Electronics
Stuck, Fabian,Dietl, Martin C.,Mei?ner, Maximilian,Sebastian, Finn,Rudolph, Matthias,Rominger, Frank,Kr?mer, Petra,Hashmi, A. Stephen K.
supporting information, (2021/12/14)
Efficient synthetic approaches for the incorporation of nitrogen into polyaromatic compounds (PACs) in different patterns as stabilising moiety for π-extended systems and modification tool for optoelectronic properties remain a challenge until today. Here
Transition-metal-free synthesis of aromatic amines via the reaction of benzynes with isocyanates
Seo, Jeong Hoon,Ko, Haye Min
supporting information, p. 671 - 674 (2018/01/19)
An unexpected reaction between benzynes and isocyanates to generate aromatic amines has been developed under transition-metal-free conditions. The in situ prepared anions formed through cleavage of the N–C bond in isocyanates, reacted with aryne precursor
CuI catalyzed sulfamidation of arylboronic acid using TsNBr2 at room temperature
Loukrakpam, Dineshwori Chanu,Phukan, Prodeep
supporting information, p. 4855 - 4858 (2017/11/29)
An expeditious protocol for amidation arylboronic acid has been developed using TsNBr2 as the nitrogen source in presence of a CuI as catalyst. Various arylboronic acids could be transformed into corresponding N-arylsulfonamide derivatives within a very short time using CuI as catalyst in presence of DBU at room temperature.