18272-61-2

Basic information

• Product Name: 2-(2-methylbut-3-en-2-yl)phenol
• CAS NO: 18272-61-2
• Molecular Formula: C₁₁H₁₄O
• Molecular Weight: 162.2283
• Mol File: 18272-61-2.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 233.3°C at 760 mmHg
• Flash Point: 104.7°C
• Density: 0.976g/cm³
• Vapor Pressure: 0.0369mmHg at 25°C
• Refractive Index: 1.524
• CAS DataBase Reference: 2-(2-methylbut-3-en-2-yl)phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-methylbut-3-en-2-yl)phenol(18272-61-2)
• EPA Substance Registry System: 2-(2-methylbut-3-en-2-yl)phenol(18272-61-2)

Safety Data

• Hazardous Substances Data: 18272-61-2(Hazardous Substances Data)

Usage

Type of compound

Phenolic compound

Usage

Antioxidant and preservative in industries such as food, cosmetics, and pharmaceuticals

Physical state

Yellow liquid

Odor

Characteristic phenolic odor

Solubility

Soluble in alcohol and ether

Antimicrobial properties

Prevents the growth of mold and bacteria

Use in synthesis

Used in the synthesis of other chemical compounds

Fragrance ingredient

Used in perfumes and soaps

Safety precautions

Can be irritating to skin and eyes; prolonged exposure should be avoided.

Upstream product

• 14309-15-0 phenyl prenyl ether 
• 59671-72-6 2-(1',1'-dimethylprop-2'-enyl)phenyl acetate 
• 19493-09-5 Methylenetriphenylphosphorane 
• 139-02-6 sodium phenoxide 
• 503-60-6 3,3-dimethyl-allyl chloride 
• 556-82-1 3-methyl-2-buten-1-ol 
• 108-95-2 phenol 

Downstream Products

• 139437-09-5 4-(2'-hydroxyphenyl)-4-methylpentanal 
• 139437-10-8 5,5-dimethyl-2,3,4,5-tetrahydro-1-benzoxepin-2-ol 

Relevant articles and documents

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InIII-catalysed tandem C-C and C-O bond formation between phenols and allylic acetates

Indium triflate catalysed tandem allylation-intramolecular hydroalkoxylation was efficiently carried out by using 1 mol-% of the catalyst under mild conditions to afford the dihydrobenzopyran ring system (chroman-type structure) in good yields. Kinetic, mechanistic and theoretical studies are also presented. Tandem allylation-intramolecular hydroalkoxylation carried out in the presence of an indium catalyst (1 mol-%) under mild conditions provides the dihydrobenzopyranring system in good yields. Kinetic, mechanistic and theoretical studies are presented.

The Stereochemistry of Organometallic Compounds. XXXV. Hydroformylation of ortho-Propenylanilines and ortho-Propenylphenols: a New Route to 4,5-Dihydro-3H-1-benzazepines

Rhodium-catalyzed hydroformylation of readily available ortho-propenylanilines gives 4,5-dihydro-3H-1-benzazepines together with small amounts of substituted 3-methylquinolines (15percent).The regioselectivity of these reactions and the hydroformylation of related ortho-propenylphenols are discussed.