183163-06-6Relevant articles and documents
An easy access to aryl azides from aryl amines under neutral conditions
Das, Jagattaran,Patil, Santoshkumar N.,Awasthi, Riti,Narasimhulu, C. Prasad,Trehan, Sanjay
, p. 1801 - 1806 (2005)
A variety of substituted aryl amines were transformed into aryl azides using t-BuONO and moist NaN3 in t-BuOH in good to excellent yields. Smooth transformation was observed with anilines, having electron withdrawing and donating groups. Both acid- and base-sensitive groups survived the reaction conditions. Georg Thieme Verlag Stuttgart.
Handling Hazards Using Continuous Flow Chemistry: Synthesis of N1-Aryl-[1,2,3]-triazoles from Anilines via Telescoped Three-Step Diazotization, Azidodediazotization, and [3 + 2] Dipolar Cycloaddition Processes
Teci, Matthieu,Tilley, Michael,McGuire, Michael A.,Organ, Michael G.
supporting information, p. 1967 - 1973 (2017/02/10)
The conversion of commercially available anilines into triazole products was realized using a telescoped three-reactor flow diazotization, azidodediazotization, and [3 + 2] dipolar cycloaddition process. The diazotization-azidodediazotization sequence was