184370-68-1

Basic information

• Product Name: Silane, tris(1-methylethyl)(4-pentynyloxy)-
• CAS NO: 184370-68-1
• Molecular Formula: C14H28OSi
• Molecular Weight: 240.461
• Mol File: 184370-68-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, tris(1-methylethyl)(4-pentynyloxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, tris(1-methylethyl)(4-pentynyloxy)-(184370-68-1)
• EPA Substance Registry System: Silane, tris(1-methylethyl)(4-pentynyloxy)-(184370-68-1)

Safety Data

• Hazardous Substances Data: 184370-68-1(Hazardous Substances Data)

Upstream product

• 5390-04-5 pent-1-yn-5-ol 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 

Downstream Products

• 1312776-19-4 methyl 5-bromo-2-methylene-6-phenyl-9-triisopropylsilyloxy-5-nonenoate 
• 1312776-31-0 (Z)-methyl 5-bromo-2-methylene-6-phenyl-9-phthalimidyl-5-nonenoate 
• 1312776-20-7 (E)-methyl 5-bromo-2-methylene-6-phenyl-9-phthalimidyl-5-nonenoate 
• 1312776-26-3 6-((triisopropylsilyl)oxy)hex-2-yn-1-yl 4-methylbenzenesulfonate 
• 1312776-25-2 3-phenyl-6-phthalimidyl-1,2-hexadiene 
• 201936-40-5 (2R,3S)-2-(tert-Butyl-diphenyl-silanyloxy)-9-triisopropylsilanyloxy-non-5-yn-3-ol 

Relevant articles and documents

Regioselective radical bromoallylation of allenes leading to 2-bromo-substituted 1,5-dienes

The regioselective radical bromoallylation of allenes proceeded efficiently in the presence of AIBN as a radical initiator to give 2-bromo-substituted 1,5-dienes in excellent yields. The addition of a bromine radical took place regioselectively onto the central carbon of allenes generating a stable allyl radical, which underwent addition/β-fragmentation reactions with allylbromides. The products could be further functionalized by Pd-catalyzed coupling reactions.