18444-54-7Relevant articles and documents
Electronic Structure of Axially Distorted Molybdenum(V) Complexes; an Absorption Spectral Study
Collison, David
, p. 2999 - 3006 (1990)
Electronic absorption spectra of a range of molybdenum(V) compplexes and - have been measured in the temperature range 4.2-300 K and in the energy range 4 000-40 000 cm-1.The absorption bands below 18 000 cm-1 have been assigned to the one-electron promotion dxy* dxz*, dyz*.Bands in the visible region have been classified as type I (dxy* dx2-y2*) or type II (in-plane ligand-to-metal charge transfer).Assignments of the absorption spectra of the chromophores MoO3+, VO2+, WO3+, MoN2+, RuN3+, and OsN3+ have been compared to produce a self-consistent assignment.