185611-85-2

Basic information

• Product Name: (2S,3R)-3-(Bis-allyloxy-phosphoryloxy)-2-((S)-2-phenylacetylamino-propionylamino)-butyric acid tert-butyl ester
• CAS NO: 185611-85-2
• Molecular Weight: 524.551
• Mol File: 185611-85-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2S,3R)-3-(Bis-allyloxy-phosphoryloxy)-2-((S)-2-phenylacetylamino-propionylamino)-butyric acid tert-butyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R)-3-(Bis-allyloxy-phosphoryloxy)-2-((S)-2-phenylacetylamino-propionylamino)-butyric acid tert-butyl ester(185611-85-2)
• EPA Substance Registry System: (2S,3R)-3-(Bis-allyloxy-phosphoryloxy)-2-((S)-2-phenylacetylamino-propionylamino)-butyric acid tert-butyl ester(185611-85-2)

Safety Data

• Hazardous Substances Data: 185611-85-2(Hazardous Substances Data)

Upstream product

• 126429-21-8 diallyl diisopropylphosphoramidite 

Relevant articles and documents

Selective enzymatic removal of protecting groups: The phenylacetamide as amino protecting group in phosphopeptide synthesis

The phenylacetamido (PhAc) amino protecting group can be removed from sensitive phosphopeptides by means of penicillin G acylase under mild conditions (pH 6.5, room temperature) and without attack on the peptide bonds, the C-terminal esters or the phosphates. In particular, under the conditions of the enzymatic reactions a β-elimination of the phosphate does not occur.