1861-48-9

Basic information

• Product Name: S-[2-(4-bromophenyl)-2-oxoethyl] O-ethyl carbonodithioate
• Synonyms: carbonodithioic acid, S-[2-(4-bromophenyl)-2-oxoethyl] O-ethyl ester; S-[2-(4-Bromophenyl)-2-oxoethyl] o-ethyl dithiocarbonate
• CAS NO: 1861-48-9
• Molecular Formula: C₁₁H₁₁BrO₂S₂
• Molecular Weight: 319.2378
• Mol File: 1861-48-9.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 424.7°C at 760 mmHg
• Flash Point: 210.6°C
• Density: 1.505g/cm³
• Vapor Pressure: 2.03E-07mmHg at 25°C
• Refractive Index: 1.624
• CAS DataBase Reference: S-[2-(4-bromophenyl)-2-oxoethyl] O-ethyl carbonodithioate(CAS DataBase Reference)
• NIST Chemistry Reference: S-[2-(4-bromophenyl)-2-oxoethyl] O-ethyl carbonodithioate(1861-48-9)
• EPA Substance Registry System: S-[2-(4-bromophenyl)-2-oxoethyl] O-ethyl carbonodithioate(1861-48-9)

Safety Data

• Hazardous Substances Data: 1861-48-9(Hazardous Substances Data)

Upstream product

• 4209-02-3 1-(4-bromophenyl)-2-chloroethan-1-one 
• 140-90-9 sodium O-ethyl dithiocarbonate 
• 140-89-6 potassium ethyl xanthogenate 
• 99-73-0 para-bromophenacyl bromide 

Downstream Products

• 105623-80-1 5-(4-bromo-benzoyl)-4-methylthio-1,3-dithiole-2-thione 
• 188999-93-1 Dithiocarbonic acid S-[4-(4-bromo-phenyl)-1-(1,3-dioxo-1,3-dihydro-isoindol-2-ylmethyl)-4-oxo-butyl] ester O-ethyl ester 
• 76173-08-5 1-(4-bromo-phenyl)-pent-4-en-1-one 
• 478800-93-0 dithiocarbonic acid S-{1-[3-(4-bromo-phenyl)-3-oxo-propyl]-heptyl} ester O-ethyl ester 
• 1164111-68-5 (E)-7-(4-bromo-phenyl)-4-(4-chloro-phenyl)-7-oxo-hept-2-enoic acid ethyl ester 
• 1164111-76-5 (E)-7-(4-bromophenyl)-4-(3-fluoro-phenyl)-7-oxo-hept-2-enoic acid ethyl ester 
• 1198087-72-7 1-(4-bromophenyl)-2-(5-methylfuran-2-yl)ethan-1-one 
• 1243579-30-7 S-[4-(4-bromo-phenyl)-1-(1,3-dioxo-1,3-dihydroisoindol-2-yl)-4-oxo-butyl]-O-ethyl dithiocarbonate 
• 1309875-73-7 O-ethyl 5-(4-bromophenyl)-5-oxo-1-phenylpentan-2-yl carbonodithioate 

Relevant articles and documents

Synthesis of pyrazolylvinyl ketones from furan derivatives

A new protocol for the synthesis of pyrazol-5-ylvinyl ketones, e.g. pyrazole-chalcones, employing furfuryl ketones as a triketone equivalent, has been developed. The reaction occurs under mild conditions and does not require the use of expensive materials

A simple method for the synthesis of furfuryl ketones and furylacetic acid derivatives

A simple preparative method has been developed for the synthesis of aryl(furfuryl) ketones, amides, and furylacetic acid esters, based on radical alkylation of furan derivatives at the α-position with O-ethyl(phenacyl)xanthogenates and phenacyl iodides in the presence of Fenton's reagent (H2O2/FeSO4·7H2O) in DMSO. The range of applicability and mechanisms for the formation of major and side products have been considered.

SYNTEZY ZWIAZKOW O POTENCJALNYM DZIALANIU RADIOUCZULAJACYM. VIII. SYNTEZY ALKILOKSANTOGENIANOW 4-CHLORO- I 4-BROMOFENACYLOWYCH

In the frame-work of search for new potential radiosensitizers a series of novel 4-chloro- and 4-bromophenacyl alkylxanthates were synthetized by reacting 4-chloro- and 4-bromophenacyl bromide with potassium alkylxanthates, in which allyl, ethyl, propyl, isopropyl, butyl, isobutyl, pentyl, isopentyl, heksyl, heptyl, octyl, isooctyl, decyl, 3-tetrahydrofurfuryl, benzyl, phenylethyl and phenylpropyl constituted the alkyl group.