18629-74-8

Basic information

• Product Name: Benzyltriethylstannane
• Synonyms: Benzyltriethylstannane
• CAS NO: 18629-74-8
• Molecular Formula: C₁₃H₂₂Sn
• Molecular Weight: 297.0238
• Mol File: 18629-74-8.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 293.4°Cat760mmHg
• Flash Point: 134.7°C
• Appearance: /
• Density: g/cm³
• Vapor Pressure: 0.00303mmHg at 25°C
• CAS DataBase Reference: Benzyltriethylstannane(CAS DataBase Reference)
• NIST Chemistry Reference: Benzyltriethylstannane(18629-74-8)
• EPA Substance Registry System: Benzyltriethylstannane(18629-74-8)

Safety Data

• Hazardous Substances Data: 18629-74-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C7H7.3C2H5.Sn/c1-7-5-3-2-4-6-7;3*1-2;/h2-6H,1H2;3*1H2,2H3;/rC13H22Sn/c1-4-14(5-2,6-3)12-13-10-8-7-9-11-13/h7-11H,4-6,12H2,1-3H3

Upstream product

• 994-31-0 chlorotriethylstannane 
• 100-39-0 benzyl bromide 
• 2767-54-6 triethyltin bromide 
• 6921-34-2 benzylmagnesium chloride 
• 1066-86-0 triethylstannyldiethylamine 
• 994-50-3 bis(triethyltin) sulfide 
• 1066-84-8 Dimethylamino-triethyl-stannan 
• 757-35-7 (chloromethyl)(triethyl)stannane 
• 1067-26-1 triethylethoxystannane 
• 14230-31-0 1-triethylstannanyl-propan-2-one 
• 83991-18-8 Triethyl-trichlormethyl-zinn 
• 4554-88-5 Acetic acid triethylstannanylmethyl ester 
• 31775-87-8 ethyl ester of triethylstannylacetic acid 
• 50490-86-3 (C₂H₅)3SnCH₂COC₆H₄-p-OCH₃ 

Downstream Products

• 18629-77-1 (C₂H₅)3SnOOCH₂C₆H₅ 
• 3646-80-8 triethyltin benzoate 
• 14275-54-8 diethyltin dibenzoate 
• 14275-51-5 Hexaaethyltristannoxan-dibenzoat 
• 3682-12-0 diethyltin(IV) oxide 
• 2943-86-4 triethyltin iodide 
• 620-05-3 iodomethylbenzene 

Relevant articles and documents

Preparation of benzylstannanes by zinc-mediated coupling of benzyl bromides with organotin derivatives. Physicochemical characterization and crystal structures

Benzyltrialkyl- (1-13) and benzyltriphenylstannanes (16-22) have been easily prepared in a one-pot synthesis via coupling reaction of benzyl bromide derivatives (C6H5CH2Br and XYC6H3CH2Br, X = H, Y = o-, m-, p-CH3, o-, m-, p-F, o-, m-Cl, and p-Br; X = o-F, Y = p-Br) with R3SnCl compounds (R = Et, Pr, Bu, and Ph) in THF/H2O (NH4Cl) medium mediated by zinc powder. Such coupling also occurs with (Bu3Sn)2O. Dibenzyldibutylstannane (15) is prepared by reaction of benzyl bromide with Bu2SnCl2 or (Bu2SnCl)2O, and (2-naphthylmethyl)tributylstannane (14) by reaction of 2-(bromomethyl)naphthalene with Bu3SnCl. 13C-and 119Sn-NMR data are reported for all compounds, and M?ssbauer data for benzyltributylstannanes 10 and 11 and benzyltriphenylstannanes 16-18 and 20-22. The crystal structures of Ph3SnBn, with Bn = o- (17) and m-ClC6H4CH2 (18) and o- (20) and m-FC6H4-CH2 (21) have been determined.