1865-12-9

Basic information

• Product Name: Benzenemethanamine, N,a-diphenyl-
• CAS NO: 1865-12-9
• Molecular Formula: C19H17N
• Molecular Weight: 259.351
• Mol File: 1865-12-9.mol
• Article Data: 98

Chemical Properties

• CAS DataBase Reference: Benzenemethanamine, N,a-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanamine, N,a-diphenyl-(1865-12-9)
• EPA Substance Registry System: Benzenemethanamine, N,a-diphenyl-(1865-12-9)

Safety Data

• Hazardous Substances Data: 1865-12-9(Hazardous Substances Data)

Upstream product

• 60-29-7 diethyl ether 
• 622-32-2 (Z)-benzaldehyde oxime 
• 10229-54-6 benzaldehyde-(O-methyl-seqcis-oxime ) 
• 17146-21-3 O-(benzyl)benzaldoxime 
• 62-53-3 aniline 
• 908093-98-1 diazodiphenylmethane 
• 103-70-8 Formanilid 
• 776-74-9 Bromodiphenylmethane 
• 606-87-1 N,N-diphenylbenzylamine 
• 90-99-3 diphenylchloromethane 
• 95-14-7 1,2,3-Benzotriazole 
• 91-01-0 1,1-Diphenylmethanol 
• 123-38-6 propionaldehyde 
• 119-61-9 benzophenone 

Downstream Products

• 122568-10-9 formic acid-(2,4-dibenzhydryl-anilide) 
• 57259-32-2 (2-aminophenyl)diphenylmethane 
• 603-38-3 4-(diphenylmethyl)aniline 
• 79817-40-6 N-benzhydryl-4-chlorobutananilide 
• 574-45-8 N-(diphenylmethylidene)phenylamine 
• 3178-23-2 dicyclohexylmethane 
• 753401-43-3 cyclohexyl-(cyclohexyl-phenyl-methyl)-amine 
• 108-91-8 cyclohexylamine 
• 119-61-9 benzophenone 
• 62-53-3 aniline 
• 1450-31-3 Thiobenzophenon 
• 1360145-10-3 N-benzhydryl-N-phenyldinaphthophosphoramidite 
• 58814-37-2 N-(4-(hydroxydiphenylmethyl)phenyl)acetamide 
• 103-84-4 Acetanilid 

Relevant articles and documents

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Silver-Catalyzed N-H Functionalization of Aryl/Aryl Diazoalkanes with Anilines

Herein, we report on the N-H functionalization reaction of primary and secondary anilines with diaryldiazoalkanes using simple AgPF6 as catalyst. We demonstrated broad applicability in the reaction of diaryldiazoalkanes with different anilines (31 examples, up to 97% yield). Furthermore, we propose a possible reaction mechanism for the N-H functionalization.

Metallic Barium: A Versatile and Efficient Hydrogenation Catalyst

Ba metal was activated by evaporation and cocondensation with heptane. This black powder is a highly active hydrogenation catalyst for the reduction of a variety of unactivated (non-conjugated) mono-, di- and tri-substituted alkenes, tetraphenylethylene, benzene, a number of polycyclic aromatic hydrocarbons, aldimines, ketimines and various pyridines. The performance of metallic Ba in hydrogenation catalysis tops that of the hitherto most active molecular group 2 metal catalysts. Depending on the substrate, two different catalytic cycles are proposed. A: a classical metal hydride cycle and B: the Ba metal cycle. The latter is proposed for substrates that are easily reduced by Ba0, that is, conjugated alkenes, alkynes, annulated rings, imines and pyridines. In addition, a mechanism in which Ba0 and BaH2 are both essential is discussed. DFT calculations on benzene hydrogenation with a simple model system (Ba/BaH2) confirm that the presence of metallic Ba has an accelerating effect.

Iron-catalysed hydroboration of non-activated imines and nitriles: Kinetic and mechanistic studies

Iron-catalysed hydroboration of imines and nitriles has been developed under low catalyst loading (1 mol%) in the presence of HBpin. A wide scope of substrate was found to smoothly undergo hydroboration, including electron releasing/withdrawing and haloge