18752-22-2

Basic information

• Product Name: triphenyl(1-propenyl)silane
• Synonyms: triphenyl(1-propenyl)silane
• CAS NO: 18752-22-2
• Molecular Weight: 300.475
• Mol File: 18752-22-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: triphenyl(1-propenyl)silane(CAS DataBase Reference)
• NIST Chemistry Reference: triphenyl(1-propenyl)silane(18752-22-2)
• EPA Substance Registry System: triphenyl(1-propenyl)silane(18752-22-2)

Safety Data

• Hazardous Substances Data: 18752-22-2(Hazardous Substances Data)

Upstream product

• 563-58-6 1,1-dichloropropene 
• 791-30-0 triphenylsilyl-lithium 
• 76-86-8 Triphenylsilyl chloride 
• 13154-14-8 1-propenylmagnesium bromide 
• 18752-21-1 allyltriphenylsilane 

Downstream Products

• 791-31-1 triphenylhydroxysilane 
• 61883-43-0 (1-Methyl-allyl)-triphenyl-silane 
• 64889-27-6 ((E)-But-1-enyl)-triphenyl-silane 
• 116385-55-8 (E)-2-Phenyl-5-triphenylsilanyl-pent-4-en-2-ol 
• 116385-52-5 (E)-1-phenyl-4-triphenylsilyl-3-buten-1-ol 
• 16939-57-4 (E)-buta-1,3-dienylbenzene 
• 116385-51-4 C₂₁H₁₉⁽²⁾HSi 
• 116385-50-3 C₂₁H₁₉⁽²⁾HSi 
• 116385-53-6 (1E,5E)-1-Phenyl-6-triphenylsilanyl-hexa-1,5-dien-3-ol 
• 116385-61-6 1-(3-Triphenylsilanyl-oxiranyl)-octan-2-ol 
• 116385-63-8 1-(3-Triphenylsilanyl-oxiranyl)-octan-2-one 

Relevant articles and documents

Convenient synthesis of isoxazolines via tandem isomerization of allyl compounds to vinylic derivatives and 1,3-dipolar cycloaddition of nitrile oxides to the vinylic compounds

A novel effective method for the synthesis of new isoxazolines via tandem isomerization of QCH(X)CH{double bond, long}CH(Y) to QC(X){double bond, long}CHCH2(Y) (Q = RO, RS, R2N, R3Si, etc.; X = H, R, OR; Y = H, R; R = alkyl, aryl) catalyzed by ruthenium complexes and 1,3-dipolar cycloaddition of the latter compounds to arenenitrile oxides is presented. The cycloaddition of QCH(X)CH{double bond, long}CH(Y) to 2,6-dichlorobenzonitrile oxide is also described. The regio- and stereoselectivity of the cycloaddition of nitrile oxide to allyl and 1-propenyl (vinylic in general) compounds is discussed.

Preparation of (Triphenylsilyl)allyl Anion and (Triphenylgermyl)allyl Anion from 1-Propenyltriphenylsilane and 1-Propenyltriphenylgermane and Their Reactions with Electrophiles

Treatment of 1-propenyltriphenylsilane with n-BuLi in THF-HMPA provides (triphenylsilyl)allyl anion which is identical with an anion derived from 2-propenyltriphenylsilane and base.Generation of (triphenylgermyl)allyl anion is also described.Addition of alkyl halides or carbonyl compounds to these anions gives the corresponding adducts regioselectively.