187536-93-2Relevant articles and documents
Fluxional Pd(II) NHC complexes - Synthesis, structure elucidation and catalytic studies
Dangalov, Miroslav,Stoyanova, Malinka,Petrov, Petar,Putala, Martin,Vassilev, Nikolay G.
, p. 1 - 14 (2016)
Four catalytically relevant Pd(II) complexes involving N-heterocyclic carbenes (NHCs) and bidentate N- and P-donor ligands were synthesized and characterized. The structures and conformations of the complexes were elucidated on the basis of combination of
Palladium-Catalyzed Cyclization: Regioselectivity and Structure of Arene-Fused C60 Derivatives
Hashikawa, Yoshifumi,Murata, Michihisa,Wakamiya, Atsushi,Murata, Yasujiro
, p. 16350 - 16358 (2017)
The palladium-catalyzed cyclization on the fullerene C60 cage has been achieved using several aryl halides and C60. This reaction was found to be accelerated by the addition of pivalic acid, which can be rationally explained by the c
Anomalous Halogen-Halogen Interaction Assists Radial Chromophoric Assembly
Niyas,Ramakrishnan, Remya,Vijay, Vishnu,Sebastian, Ebin,Hariharan, Mahesh
supporting information, p. 4536 - 4540 (2019/02/26)
The design of highly efficient supramolecular architectures that mimic competent natural systems requires a comprehensive knowledge of noncovalent interactions. Halogen bonding is an excellent noncovalent interaction that forms halogen-halogen (X2) as well as trihalogen interacting synthons. Herein, we report the first observation of a symmetric radial assembly of chromophores (R3c space group) composed of a stable hexabromine interacting synthon (Br6) that further push the limits of our understanding on the nature, role, and potential of noncovalent halogen bonding. Contrary to the destabilization proposed for Type-I X2 interactions, Br6-synthon-possessing Type-I X2 interactions exhibit a stabilizing nature owing to the exchange-correlation component. The radial assembly of chromophores is further strengthened by intermolecular through-space charge transfer interaction. Br6-synthon-driven 3-fold symmetric radial assembly render a lattice structure that reminisces the chromophoric arrangement in the light harvesting system 2 of purple bacteria.
Suitable for UV - LED light curing of the naphthalimide aryl benzyl [...] photoinitiator and preparation method and application
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Paragraph 0012; 0032; 0036, (2019/03/25)
The invention discloses a suitable for UV - LED light curing of the naphthalimide aryl benzyl [...] photoinitiators, relates to a photosensitive polymer field, based on the existing light initiator in UV - LED under irradiation of light source caused by t