18779-57-2

Basic information

• Product Name: 1-O,2-O,3-O,4-O,5-O,6-O-Hexaacetyl-muco-inositol
• Synonyms: 1-O,2-O,3-O,4-O,5-O,6-O-Hexaacetyl-muco-inositol;muco-Inositol hexaacetate
• CAS NO: 18779-57-2
• Molecular Formula: C₁₈H₂₄O₁₂
• Molecular Weight: 0
• Mol File: 18779-57-2.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1-O,2-O,3-O,4-O,5-O,6-O-Hexaacetyl-muco-inositol(CAS DataBase Reference)
• NIST Chemistry Reference: 1-O,2-O,3-O,4-O,5-O,6-O-Hexaacetyl-muco-inositol(18779-57-2)
• EPA Substance Registry System: 1-O,2-O,3-O,4-O,5-O,6-O-Hexaacetyl-muco-inositol(18779-57-2)

Safety Data

• Hazardous Substances Data: 18779-57-2(Hazardous Substances Data)

Upstream product

• 93-59-4 Perbenzoic acid 
• 67-66-3 chloroform 
• 526-87-4 (+/-)-Conduritol F 
• 64-19-7 acetic acid 
• 108-24-7 acetic anhydride 
• 113973-61-8 1,2,3,6-tetra-O-acetyl-muco-inositol 
• 402724-04-3 L-4-O-benzyl-3-O-1,2-O-(2,2,2-trichloroethylidene)-3-O-cyclohexylcarbamoyl-5-O-methyl-muco-inositol 
• 404351-03-7 L-1-O-benzyl-6-O-cyclohexylcarbamoyl-4,5-O-ethylidene-2-O-methyl-muco-inositol 
• 526-87-4 conduritol A 
• 109526-05-8 conduritol A tetraacetate 
• 18685-70-6 chiro-inositol 
• 17793-95-2 (1RS,2RS)-cyclohexa-3,5-diene-1,2-diol 
• 64288-00-2 trans-cyclohexa-3,5-diene-1,2-diyl diacetate 
• 64-17-5 ethanol 

Downstream Products

• 488-55-1 muco-inositol 

Relevant articles and documents

Site-selective benzoin-type cyclization of unsymmetrical dialdoses catalyzed by N-heterocyclic carbenes for divergent cyclitol synthesis

A highly site-selective N-heterocyclic carbene (NHC)-catalyzed benzoin-type cyclization of unsymmetrical dialdoses is developed to enable a divergent cyclitol synthesis. The choice of chiral NHCs and protecting groups affects the site-selectivity. The resulting inososes are converted into epi-, muco- and myo-inositols, and their chiral protected derivatives are formed in good yields.

Catalytic One-Pot Osmylation of Cyclohexadienes: Stereochemical and Conformational Studies of the Resulting Polyols

Catalytic double osmylation is described for a series of cyclohexadienes in acetone/H2O in the presence of the co-oxidant N-methylmorpholine N-oxide (NMO).The formation of polyols occurred stereospecifically with cyclohexadienes 3, 7, and 11a, leading thereby to tetrols 5a, and 9a and to allo-inositol (14a), respectively.To the contrary, trans-cyclohexadiene-diol 15a gave a mixture of the stereoisomeric inositols 18a (epi), 19a (neo), and 20a (chiro).High-field NMR let to clearcut conformational analyses of the polyhydroxylated derivatives.

The structure of adenomycin (C19-97 substance)

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