187835-67-2Relevant articles and documents
Reactions of Polyfluoroaromatic Organozinc Compounds with Oxalyl Chloride in DMF. Synthesis of Polyfluoroaromatic Aldehydes
Vinogradov,Platonov
, p. 2264 - 2272 (2021/02/12)
Abstract: The reaction of polyfluoroaromatic organozinc compounds with oxalyl chloride in DMF proceeds involving the Vilsmeier–Haack reagent with the formation of polyfluoroaromatic aldehydes as the major products. The use of CuI makes it possible to incr
Transformations of perfluoroxylenes and perfluoro-p-cymene under the action of Zn(Cu)-DMF-H2O
Krasnov, Vyacheslav I.,Platonov, Vyacheslav E.,Beregovaya, Irina V.,Shchegoleva, Lyudmila N.
, p. 1797 - 1812 (2007/10/03)
Perfluorinated xylenes and perfluoro-para-cymene undergo hydrodefluorination under the action of Zn(Cu)-DMF-H2O. Hydrogen enters mainly at the benzyl position of para-dialkylbenzenes and at the para position to perfluoroalkyl groups of perfluor