188-55-6Relevant articles and documents
A facile synthesis of functionalized 7,8-diaza[5]helicenes through an oxidative ring-closure of 1,1'-binaphthalene- 2,2'-diamines (BINAMs)
Takeda, Youhei,Okazaki, Masato,Maruoka, Yoshiaki,Minakata, Satoshi
, p. 9 - 15 (2015)
A facile and moderately functional-group-tolerant synthetic method for the preparation of 7,8-diaza[5]helicenes has been developed. It comprises of an oxidative ring-closing process of 1,1'-binaphthalene-2,2'-diamine (BINAM) derivatives with a chlorinecontaining oxidant (t - BuOCl) in the presence of a base (2,6-lutidine). In addition the basic physicochemical properties of newly synthesized compounds have been investigated.
A simple approach for the synthesis of 7,8-diaza[5]helicene
Caronna, Tullio,Fontana, Francesca,Mele, Andrea,Sora, Isabella Natali,Panzeri, Walter,Vigano, Luca
, p. 413 - 416 (2008/09/20)
An oxidative route for the formation of 7,8-diaza[5]helicene and the corresponding N-oxides in high yields was developed. A mechanism of formation and possible interconversion of these products is put forward. Reduction of the N-oxides provided the title compound in quantitative yield. Georg Thieme Verlag Stuttgart.