188123-54-8

Basic information

• Product Name: (1S,2R,6S,7S,8S)-8-(tert-Butyl-diphenyl-silanyloxy)-5-((S)-3-methyl-heptanoyl)-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]decan-4-one
• Synonyms: (1S,2R,6S,7S,8S)-8-(tert-Butyl-diphenyl-silanyloxy)-5-((S)-3-methyl-heptanoyl)-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]decan-4-one
• CAS NO: 188123-54-8
• Molecular Weight: 533.783
• Mol File: 188123-54-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (1S,2R,6S,7S,8S)-8-(tert-Butyl-diphenyl-silanyloxy)-5-((S)-3-methyl-heptanoyl)-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]decan-4-one(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2R,6S,7S,8S)-8-(tert-Butyl-diphenyl-silanyloxy)-5-((S)-3-methyl-heptanoyl)-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]decan-4-one(188123-54-8)
• EPA Substance Registry System: (1S,2R,6S,7S,8S)-8-(tert-Butyl-diphenyl-silanyloxy)-5-((S)-3-methyl-heptanoyl)-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]decan-4-one(188123-54-8)

Safety Data

• Hazardous Substances Data: 188123-54-8(Hazardous Substances Data)

Upstream product

• 109-72-8 n-butyllithium 
• 188123-35-5 Benzoic acid (1S,2R,3S,4R)-3-tert-butoxycarbonylamino-bicyclo[2.2.1]hept-5-en-2-yl ester 
• 188123-36-6 Benzoic acid (1R,2R,3R,7S,8S,10R)-2-iodo-5-oxo-4-oxa-6-aza-tricyclo[5.2.1.0^3,8]dec-10-yl ester 
• 188123-37-7 Benzoic acid (1S,3S,7S,8S,10R)-5-oxo-4-oxa-6-aza-tricyclo[5.2.1.0^3,8]dec-10-yl ester 
• 188123-34-4 (1S,2R,6S,7R)-4-Oxo-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]dec-8-ene-5-carboxylic acid tert-butyl ester 
• 188123-39-9 (1S,2R,6S,7S,8S)-8-Hydroxy-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]decan-4-one 
• 188123-38-8 (1S,3S,7S,8S,10R)-10-Hydroxy-4-oxa-6-aza-tricyclo[5.2.1.0^3,8]decan-5-one 
• 139240-75-8 (+)-(1S,2R,6S,7R)-3-oxa-5-azatricyclo[5.2.1.0^2,6]dec-8-en-4-one 
• 59614-85-6 (-)-(S)-3-methylheptanoic acid 
• 188123-40-2 (1S,2R,6S,7S,8S)-8-(tert-Butyl-diphenyl-silanyloxy)-3-oxa-5-aza-tricyclo[5.2.1.0^2,6]decan-4-one 

Downstream Products

• 61169-84-4 (S)-3-methylheptan-1-ol 

Relevant articles and documents

Sterically constrained tricyclic 2-oxazolidinone as excellent chiral auxiliary

A new class of conformationally rigid 2-oxazolidinones with effectively bulky substituents, derived from the [4+2] cycloadduct of cyclopentadiene and a-oxazolone, serve as extremely powerful chiral auxiliaries for asymmetric alkylations, Diels-Alder reactions and conjugate addition reactions.