18816-18-7Relevant articles and documents
Hydrogenolysis of Polysilanes Catalyzed by Low-Valent Nickel Complexes
Comas-Vives, Aleix,Eiler, Frederik,Grützmacher, Hansj?rg,Pribanic, Bruno,Trincado, Monica,Vogt, Matthias
supporting information, p. 15603 - 15609 (2020/04/29)
The dehydrogenation of organosilanes (RxSiH4?x) under the formation of Si?Si bonds is an intensively investigated process leading to oligo- or polysilanes. The reverse reaction is little studied. To date, the hydrogenolysis of Si?Si bonds requires very harsh conditions and is very unselective, leading to multiple side products. Herein, we describe a new catalytic hydrogenation of oligo- and polysilanes that is highly selective and proceeds under mild conditions. New low-valent nickel hydride complexes are used as catalysts and secondary silanes, RR′SiH2, are obtained as products in high purity.
Reactivity of group 4 benzamidinate complexes towards mono- and bis-substituted silanes and 1,5-hexadiene
Volkis, Victoria,Averbuj, Claudia,Eisen, Moris S.
, p. 1940 - 1950 (2007/10/03)
Zirconium and titanium bis(benzamidinate) dimethyl complexes were found to be active catalytic precursors for the oligomerization of mono- and bis-substituted silanes. The activation of such complexes, by an excess of MAO or by an equimolar amount of B(C
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Hassler, Karl,Koell, Wolfgang
, p. 157 - 167 (2007/10/03)
Partially fluorinated aryltrisilanes FnSi3Ar8-n, FnHmSi3Ar8-n-m or FnClHmSi3Ar7-n-m (Ar = phenyl and/or p-tolyl) have been synthesized
