189154-14-1

Basic information

• Product Name: Naphthalene, 1-(3,3-diphenyl-2-propenyl)-
• CAS NO: 189154-14-1
• Molecular Formula: C25H20
• Molecular Weight: 320.434
• Mol File: 189154-14-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Naphthalene, 1-(3,3-diphenyl-2-propenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Naphthalene, 1-(3,3-diphenyl-2-propenyl)-(189154-14-1)
• EPA Substance Registry System: Naphthalene, 1-(3,3-diphenyl-2-propenyl)-(189154-14-1)

Safety Data

• Hazardous Substances Data: 189154-14-1(Hazardous Substances Data)

Upstream product

• 189154-06-1 3-(1-naphthyl)-1,1-diphenylpropanol 
• 13026-12-5 3-(1-naphthyl)propenoic acid 
• 36818-50-5 ethyl 3-(naphth-1-yl)propanoate 
• 98978-43-9 ethyl 3-(naphthalen-1-yl)acrylate 
• 530-48-3 1,1-Diphenylethylene 

Relevant articles and documents

Nickel-Catalyzed Benzylation of Aryl Alkenes with Benzylamines via C-N Bond Activation

We have developed the first example of nickel-catalyzed Heck-type benzylation of aryl olefins with various benzylamines as benzyl electrophiles, and the benzylic C-N bond cleavage was efficiently promoted by the amine-I2 charge transfer complex (CT complex). The combination of low-cost NiCl2 and I2 has been found to facilitate Heck reaction of tertiary benzylamines and alkenes into various benzyl-substituted alkenes in good to excellent yields. This unconventional Heck reaction is proposed to go through initially the formation of a benzylic radical via oxidative addition of the C-N bond with Ni(0), then capturing by aryl alkene via radical addition, followed by single-electron transfer redox and proton abstraction without oxidant and external base.