19025-36-6Relevant articles and documents
Applying the Power of Reticular Chemistry to Finding the Missing alb-MOF Platform Based on the (6,12)-Coordinated Edge-Transitive Net
Chen, Zhijie,Weseliński, ?ukasz J.,Adil, Karim,Belmabkhout, Youssef,Shkurenko, Aleksander,Jiang, Hao,Bhatt, Prashant M.,Guillerm, Vincent,Dauzon, Emilie,Xue, Dong-Xu,O’Keeffe, Michael,Eddaoudi, Mohamed
, p. 3265 - 3274 (2017)
Highly connected and edge-transitive nets are of prime importance in crystal chemistry and are regarded as ideal blueprints for the rational design and construction of metal-organic frameworks (MOFs). We report the design and synthesis of highly connected
A new stable porous Pr-organic framework constructed by multi-iodine-substituted aromatic polycarboxylates: Synthesis, characterization, and selective adsorption of dyes
Sun, Ying,Bai, Feng Ying,Min Wang, Xue,Wang, Yu,Xian Sun, Li,Heng Xing, Yong
, p. 1560 - 1578 (2019)
Poly[tris(dimethylformamide)(μ3-2,4,6-triiodol-1,3,5-benzene tricarboxylic acid)-praseodymium (III)] {Pr(TIBTC)(DMF)3}n (1) (H3TIBTC = 2,4,6-triiodo-1,3,5-benzene tricarboxylic acid) was synthesized by the reaction of Pr(NO3)3·6H2O and H3TIBTC at 85°C in a pyrex vial. 1 was characterized by elemental analysis, IR, UV–vis, TGA, PXRD, and atomic force microscopy analytical means. Each of the central Pr ions and the three carboxyl groups from the same ligand constitute a SBU, which is then joined by a carboxyl group to form a building block. In order to further explore the functional properties of 1, we used this compound for adsorption experiments. It is found that 1 can effectively adsorb anionic dyes in aqueous solutions. In particular, there is a good adsorption efficiency for coomassie brilliant blue R-250. Therefore, 1 shows good prospects for selective adsorption of anionic dyes from wastewater solution.
Water-Stable In(III)-Based Metal-Organic Frameworks with Rod-Shaped Secondary Building Units: Single-Crystal to Single-Crystal Transformation and Selective Sorption of C2H2 over CO2 and CH4
Guo, Zhen-Ji,Yu, Jiamei,Zhang, Yong-Zheng,Zhang, Jian,Chen, Ya,Wu, Yufeng,Xie, Lin-Hua,Li, Jian-Rong
, p. 2188 - 2197 (2017)
Three new water-stable In(III)-based metal-organic frameworks, namely, [In3(TTTA)2(OH)3(H2O)]·(DMA)3 (BUT-70, DMA = N,N-dimethylacetamide), [In3(TTTA)2(CH3O)3/su
1,3,5-triiodo-2,4,6-trimethylbenzene at 293 K
Boudjada,Hernandez,Meinnel,Mani,Paulus
, p. 1106 - 1108 (2001)
In the structure of triiodomesitylene (1,3,5-triiodo-2,4,6-trimethylbenzene), C9H9I3, at 293 K, the benzene ring is found to be significantly distorted from ideal D6h symmetry; the average endocyclic angles faci
Methyl-restricted rotor rotation on the stator produces high-efficiency fluorescence emission: A new strategy to achieve aggregation-induced emission
Yang, Haicheng,Zhou, Xinyue,Hui, Tianqi,Han, Yingying,Jiang, Xiaonan,Yan, Jie
, p. 12078 - 12084 (2019)
At present, we have realized that the aggregation-induced emission (AIE) achieves the purpose of fluorescence enhancement by restricting rotations to reduce intermolecular or intramolecular energy loss. Based on this idea, we synthesized a novel fluorene-