19029-50-6 Usage
Description
Perchloric Acid-d, also known as deuterated Perchloric Acid, is a variant of the common Perchloric Acid (P286000) where one or more hydrogen atoms are replaced by deuterium, a stable isotope of hydrogen. This modification results in a clear colorless solution with unique chemical properties that make it suitable for various applications.
Uses
Used in Electrochemistry:
Perchloric Acid-d is used as an electrolyte in electrochemical processes due to its ability to enhance the efficiency of reactions involving deuterium. This property makes it particularly useful in research and industrial applications where deuterated compounds are required.
Used in Chemical Synthesis:
In the field of chemical synthesis, Perchloric Acid-d serves as a reducing agent, leveraging the unique properties of deuterium to facilitate specific chemical reactions that may not be possible or as efficient with the non-deuterated form of Perchloric Acid.
Used in Analytical Chemistry:
Perchloric Acid-d is also utilized in analytical chemistry as a reagent for the analysis of samples, taking advantage of the distinct characteristics of deuterium to provide more accurate and reliable results.
Used in Nuclear Magnetic Resonance (NMR) Spectroscopy:
In NMR spectroscopy, Perchloric Acid-d is employed as a deuterated solvent or reagent to study the structure and dynamics of molecules, providing valuable insights into their properties and interactions.
Used in Isotope Labeling:
Perchloric Acid-d is used for isotope labeling in biological and chemical research, allowing scientists to track the movement and behavior of deuterated compounds within complex systems.
Used in the Production of Heavy Water:
Perchloric Acid-d contributes to the production of heavy water (D2O), which is essential in various applications, including nuclear reactors as a neutron moderator and in scientific research for studying the effects of isotopic substitution on chemical reactions and biological processes.
Check Digit Verification of cas no
The CAS Registry Mumber 19029-50-6 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,9,0,2 and 9 respectively; the second part has 2 digits, 5 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 19029-50:
(7*1)+(6*9)+(5*0)+(4*2)+(3*9)+(2*5)+(1*0)=106
106 % 10 = 6
So 19029-50-6 is a valid CAS Registry Number.
InChI:InChI=1/ClHO4/c2-1(3,4)5/h(H,2,3,4,5)/i/hD
19029-50-6Relevant articles and documents
IR absorption spectroscopy of polarized states of the [D 2O...D-OD2]+ ion in crystalline deuterodioxonium perchlorate
Karelin,Nikitina
, p. 1805 - 1810 (2006)
Polymorphism of crystalline DClO4?2D2O with 99 at % D has been studied by IR absorption spectroscopy. A new phase has been found, which is easy to identify based on some spectral indications: the spectra show a strong broad band at 2125 cm-1 due to vs,as(D 3O) vibrations of the deuterodioxonium group and a rather narrow strong band at 2506 cm-1 due to the vas(D2O) vibrations of the neutral molecular group. The continuous band v as(O...D...O) typical of the intracationic hydrogen bond in D 5O 2 + ClO 4 - is absent in this case. These features point to considerable polarization of the deuterooxonium cation [D2O...D-OD2]+. Its low symmetry is explained by a considerable displacement of the bridging D atom from the center of the strong hydrogen bond to one of the two D2O molecules induced by asymmetric interactions in the crystal field. The ClO 4 - ions bound by the hydrogen bonds of dioxonium are also in low-symmetry positions. Upon the crystallization of DClO4? 2D2O with ≥10 at % H, a polymorphic isotope effect is observed: the crystal structure depends on H-D isotope dilution, the conditions of thermal treatment of all samples being the same. Nauka/Interperiodica 2006.
Mechanism of the effect of proton hydrates on the parameters of a ClO 4-?HClO4 hydrogen bond in liquid oxonium and dioxonium perchlorates
Karelin
, p. 1541 - 1550 (2008/10/08)
IR and Raman spectroscopy is employed to study hydrogen bonds between the ions and molecules of perchloric and deuteroperchloric acids in liquid electrolytes of composition HClO4 · nH2O and DClO4 · nD2O, where n = 1-2. The signatures of solvation of the ClO4- ion by proton hydrates and simultaneously by HClO4 (DClO4) molecules are discovered. The parameters of a hydrogen bond formed by ClO4- and HClO4 are determined. A mechanism is proposed to describe the effect of proton hydrates on these parameters.
