19061-38-2

Basic information

• Product Name: 9,10-Epoxyanthracene, 9,10-dihydro-9,10-diphenyl-
• CAS NO: 19061-38-2
• Molecular Formula: C26H18O
• Molecular Weight: 346.428
• Mol File: 19061-38-2.mol
• Article Data: 17

Chemical Properties

• CAS DataBase Reference: 9,10-Epoxyanthracene, 9,10-dihydro-9,10-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 9,10-Epoxyanthracene, 9,10-dihydro-9,10-diphenyl-(19061-38-2)
• EPA Substance Registry System: 9,10-Epoxyanthracene, 9,10-dihydro-9,10-diphenyl-(19061-38-2)

Safety Data

• Hazardous Substances Data: 19061-38-2(Hazardous Substances Data)

Upstream product

• 117341-16-9 2-<(2-Acetoxyethyl)sulfinyl>aniline 
• 462-06-6 fluorobenzene 
• 5471-63-6 1,3-diphenylisobenzofuran 
• 108-86-1 bromobenzene 
• 583-55-1 1-Bromo-2-iodobenzene 
• 17763-67-6 Phenyl triflate 
• 108-90-7 chlorobenzene 
• 129112-26-1 2-iodophenyltrifluoromethanesulfonic acid 
• 533-58-4 2-Iodophenol 
• 89466-08-0 2-hydroxyphenyl boronic acid 
• 108-95-2 phenol 
• 1339957-79-7 1-acetoxy-1H-1λ(3)-benzo[d][1,2,3]-iodoxoborol-3-ol 
• 7111-67-3 1,3-diphenyl-1,3-dihydroisobenzofuran 
• 1609119-99-4 2-(p-tolylsulfinyl)phenyl triflate 

Downstream Products

• 6318-17-8 anthranol 
• 1499-10-1 9,10-diphenylanthracene 

Relevant articles and documents

Acylalkylation of Arynes Generated from o-Iodoaryl Triflates with Hydrosilanes and Cesium Fluoride

An efficient method to generate aryne intermediates from o-iodoaryl triflates triggered by triethylsilane and cesium fluoride is disclosed. This method realized the acylalkylation of arynes using easily available o-iodoaryl triflate-type precursors, which was difficult when using conventional nucleophilic activators. A wide range of (hetero)arenes including various fused benzothiazoles were successfully synthesized from o-iodoaryl triflates by virtue of their good accessibility and divergent transformations of aryne intermediates.

One-Pot Generation of Functionalized Benzynes from Readily Available 2-Hydroxyphenylboronic Acids

We developed a one-pot method for the generation of benzynes from a range of readily available 2-hydroxyphenylboronic acids. This method features the in situ activation of both boronic acid and hydroxyl groups of the substrate to enhance benzyne generation at 60 °C. Such mild conditions facilitate the generation of functionalized benzynes that immediately react with diverse arynophiles to produce multisubstituted fused benzenes.

ortho-Difunctionalization of arynes by LiZnEt2(TMP)-mediated deprotonative zincation/elimination of aryl triflates

Generation of arynes from aryl triflates has been achieved using lithium diethyl(tetramethylpiperidyl)-zincate base LiZnEt2(TMP), via a directed ortho-deprotonative zincation and subsequent elimination of the triflate group. The aryne formation